Anisotropic etching of single-crystalline solar cells is used to increase the light absorption and surface area, which can improve the conversion efficiency. However, the conventional anisotropic etching process is limited for increasing surface area. For high-efficiency solar cells, unique surface structures are necessary. We present a new two-step texture process that involves combining dry etching and wet etching to produce a high-aspect-ratio surface structure for high-efficiency solar cells. Using this process, we achieved pillar-type surface structure with 1:1.9 aspect ratios in reactive ion etching (RIE), and the aspect ratio was increased further to 1:2.6 by the anisotropic wet etching process. The reflectance of the c-Si wafer was reduced from 24% to 12% by this two-step texturing process. This new technique can be used to increase the aspect ratio and surface area for high-efficiency c-Si solar cells.
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http://dx.doi.org/10.1166/jnn.2013.8122 | DOI Listing |
J Phys Chem Lett
January 2025
Synchrotron SOLEIL, L'Orme des Merisiers, Départementale 128, 91190 Saint-Aubin, France.
We study the influence of electrical biasing on the modification of the chemical composition and electrical performance of perovskite solar cells (PSCs) by coupling electrochemical impedance spectroscopy (EIS) and scanning transmission X-ray microscopy (STXM) techniques. EIS reveals the formation of charge accumulation at the interfaces and changes in the resistive and capacitive properties. STXM study on PSCs after applying a strong electric field for a long biasing time indicates the breakdown of methylammonium (MA) cation, promoting iodide ions to migrate and create defects at the interface.
View Article and Find Full Text PDFAdv Mater
January 2025
Department of Applied Physical Sciences, University of North Carolina at Chapel Hill, Chapel Hill, NC, 27599, USA.
Perovskite technologies has taken giant steps on its advances in only a decade time, from fundamental science to device engineering. The possibility to exploit this technology on a thin flexible substrate gives an unbeatable power to weight ratio compares to similar photovoltaic systems, opening new possibilities and new integration concepts, going from building integrated and applied photovoltaics (BIPV, BAPV) to internet of things (IoT). In this perspective, the recent progress of perovskite solar technologies on flexible substrates are summarized, focusing on the challenges that researchers face upon using flexible substrates.
View Article and Find Full Text PDFSmall
January 2025
Faculty of Physics and Astronomy, Adam Mickiewicz University, Poznan, 61-614, Poland.
The behavior of triple-cation mixed halide perovskite solar cells (PSCs) under ultrashort laser pulse irradiation at varying fluences is investigated, with a focus on local heating effects observed in femtosecond transient absorption (TA) studies. The carrier cooling time constant is found to increase from 230 fs at 2 µJ cm⁻ to 1.3 ps at 2 mJ cm⁻ while the charge population decay accelerates from tens of nanoseconds to the picosecond range within the same fluence range.
View Article and Find Full Text PDFNanoscale Adv
January 2025
Université de Lorraine, CNRS, LRGP F-54000 Nancy France
Water-dispersible core/shell CuInZnSe/ZnS (CIZSe/ZnS) quantum dots (QDs) were efficiently synthesized under microwave irradiation using -acetylcysteine (NAC) and sodium citrate as capping agents. The photoluminescence (PL) emission of CIZSe/ZnS QDs can be tuned from 593 to 733 nm with varying the Zn : Cu molar ratio in the CIZSe core. CIZSe/ZnS QDs prepared with a Zn : Cu ratio of 0.
View Article and Find Full Text PDFACS Energy Lett
January 2025
Department of Chemistry and Centre for Processable Electronics, Molecular Sciences Research Hub, Imperial College London, London W12 0BZ, U.K.
Antisolvent treatment is used in the fabrication of perovskite films to control grain growth during spin coating. We study widely incorporated aromatic hydrocarbons and aprotic ethers, discussing the origin of their performance differences in 2D/3D Sn perovskite (PEAFASnI) solar cells. Among the antisolvents that we screen, diisopropyl ether yields the highest power conversion efficiency in solar cells.
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