Solid state anion-π interactions involving polyhalides.

Dalton Trans

Institut für Organische Chemie, RWTH Aachen, Landoltweg 1, 52074 Aachen, Germany.

Published: January 2014

The stabilization of polyhalides in the solid state with the support of electron-deficient pentafluorophenyl groups is described. Furthermore, a synthetic approach towards the sensitive tetraiodide dianion is described and ESI mass spectrometric evidence for its presence in solution is reported.

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Source
http://dx.doi.org/10.1039/c3dt52960fDOI Listing

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