Biodegradation tests were conducted on solidified waste forms containing ion exchange resins contaminated with high levels of radioactive nuclides. These tests were part of a program to test waste forms in accordance with the U.S. NRC Branch Technical Position on Waste Forms. Small waste forms were manufactured using two different solidification agents, Portland Type I-II cement and vinyl ester-styrene (VES). Ion exchange material was taken from a filter system which had been used to remove radionuclides from highly contaminated water. As specified by NRC, the waste forms were evaluated for their resistance to biological degradation using the G21 and G22 procedures of the American Society for Testing Materials (ASTM). Results showed that microbial growth can be supported by the VES waste forms. The particular organisms used in the tests did not grow in the presence of the cement waste forms. It is also shown that the ASTM tests specified in the Technical Position are not suitable for the use intended. A different testing methodology is recommended which would provide direct verification of waste form integrity.
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http://dx.doi.org/10.1007/BF00394515 | DOI Listing |
Cryst Growth Des
January 2025
Department of Chemical Sciences, Bernal Institute, University of Limerick, Limerick V94 T9PX, Republic of Ireland.
Solid-state synthesis is an approach to organic synthesis that is desirable because it can offer minimal or no solvent waste, high yields, and relatively low energy footprints. Herein, we report the solid-state synthesis of a novel Schiff base, 4-{()-[(4-methylpyridin-3-yl)imino]methyl}benzoic acid (), synthesized through the reaction of an amine and an aldehyde. was prepared via solvent-drop (water) grinding (SDG) on a multigram scale with 97% yield and was characterized using FTIR, H NMR, and SCXRD.
View Article and Find Full Text PDFWaste Manag
January 2025
Department of Mechanical Engineering, University of Alberta, 10-203 Donadeo Innovation Centre for Engineering, Edmonton, Alberta T6G 1H9, Canada. Electronic address:
Bitumen-derived petcoke contains significant quantities of vanadium, recoverable from the fly ash formed during combustion. Despite efforts to process vanadium recovery from petcoke, detailed cost information, critical for stakeholders and decision-makers, remains absent in the public domain. To address this gap, we developed data-intensive techno-economic models specifically for vanadium recovery from petcoke fly ash.
View Article and Find Full Text PDFWaste Manag
January 2025
Centre for Nutrition and Food Sciences, Queensland Alliance for Agriculture and Food Innovation (QAAFI), The University of Queensland, Brisbane, Queensland 4072, Australia; School of Agriculture and Food Sustainability, Faculty of Science, University of Queensland, Brisbane, Queensland 4072, Australia.
Black soldier fly larvae (BSFL) can valorise different organic matter and yield a product of high nutritional value. The lack of knowledge about the microbial safety of BSFL grown on different organic waste streams influences the commercialisation of BSFL as stockfeed ingredient. This study evaluates the microbial safety of BSFL grown on five different commercial food waste streams collected from two commercial production facilities.
View Article and Find Full Text PDFSmall
January 2025
School of Materials and Physics & Center of Mineral Resource Waste Recycling, China University of Mining and Technology, Xuzhou, Jiangsu, 221116, China.
Designing spent graphite anodes from lithium-ion batteries (LIBs) for applications beyond regenerated batteries offers significant potential for promoting the recycling of spent LIBs. The battery-grade graphite, characterized by a highly graphitized structure, demonstrates excellent conductive loss capabilities, making it suitable for microwave absorption. During the Li-ion intercalation and deintercalation processes in battery operation, the surface layer of spent graphite (SG) becomes activated, forming oxygen-rich functional groups that enhance the polarization loss mechanism.
View Article and Find Full Text PDFBiomed Res Int
January 2025
Center for Personalized Nanomedicine, Australian Institute for Bioengineering & Nanotechnology (AIBN), The University of Queensland, Brisbane, Queensland, Australia.
Environmental pollution has been a significant concern for the last few years. The leather industry significantly contributes to the economy but is one of Bangladesh's most prominent polluting industries. It is also responsible for several severe diseases such as cancer, lung diseases, and heart diseases of leather workers because they use bleaching agents and chemicals, and these have numerous adverse effects on human health.
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