Silver-catalyzed vinylogous fluorination of vinyl diazoacetates.

Org Lett

Department of Chemistry, Emory University, 1515 Dickey Drive, Atlanta, Georgia 30322, United States.

Published: December 2013

A silver-catalyzed vinylogous fluorination of vinyl diazoacetates to generate γ-fluoro-α,β-unsaturated carbonyls is presented. Application of this method to the fluorination of farnesol and steroid derivatives was achieved.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3880583PMC
http://dx.doi.org/10.1021/ol403017eDOI Listing

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