Quantifying the effectiveness of perceived best management practices (BMPs) at the field and landscape-scale is difficult, so paired watershed studies are used to detect water quality improvements. We evaluated concentrations of NO-N discharged from three tiled Iowa watersheds during a 4-yr period to assess their suitability for a paired watershed approach. Our objectives were to evaluate similarities in physical characteristics, concentration patterns, and correlation among the three paired sites and perform a minimum detectable change (MDC) analysis on paired site configurations. The study results demonstrate that concentration variability within and between sample sites affected correlation among the paired basins, even though the physical characteristics of the basins are quite similar. Restricting comparisons to the active tile drainage period (March-July) improved correlations. The lack of a suitable correlation will impair the ability to detect changes expected to result from BMP implementation. The MDC for NO-N concentration change detection varied from 6.9 to 12.9% and averaged 8% for the best control-treatment pair. To ensure that conservation resources are being used effectively, implemented BMPs should focus on practices capable of achieving at least this magnitude of change. These practices may include reduced fertilizer applications, adoption of cover crops, and land use change.
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http://dx.doi.org/10.2134/jeq2013.03.0085 | DOI Listing |
Sci Total Environ
January 2025
US Department of Agriculture, Agriculture Research Service, Hydrology and Remote Sensing Laboratory, Beltsville, MD, United States of America.
Metolachlor is the most heavily used member of acetanilide herbicides, which are noted for forming highly soluble metabolites in root zone soils soon after field application. The two primary metabolites of metolachlor, metolachlor ethane sulfonic acid (MESA) and metolachlor oxanilic acid (MOXA), retain the same chiral chemistry as their source and are important tracers of nitrate loading from agricultural cropland. New analytical methods for separating the isomers of MESA and MOXA, enable studies assessing changes in the abundance of atropisomer pairs of the carbon chiral enantiomers in environmental samples.
View Article and Find Full Text PDFWater Res
December 2024
Key Laboratory of Lake and Watershed Science for Water Security, Nanjing Institute of Geography and Limnology, Chinese Academy of Sciences, Nanjing 211135, China; Sino-Danish Centre for Education and Research, University of Chinese Academy of Sciences, Beijing 100039, China; Poyang Lake Wetland Research Station, Nanjing Institute of Geography and Limnology, Chinese Academy of Sciences, Jiujiang 332899, China. Electronic address:
Flash drought (FD) events induced by climate change may disrupt the normal hydrological regimes of floodplain lakes and affect the plant-microbe mediated dissimilatory nitrate reduction (DNR), i.e., denitrification, anammox and dissimilatory nitrate reduction to ammonium (DNRA), thus having important consequences for nitrous oxide (NO) emissions and nitrogen (N) retention.
View Article and Find Full Text PDFJ Environ Manage
January 2025
71 Smith Ave., Bureau of Water Supply, New York City Department of Environmental Protection, Kingston, NY, 12401, USA.
The paired watershed monitoring approach is widely used to investigate hydrologic processes and water quality, providing streamflow and water quality records for long-term trend analysis, as well as data for developing and testing hydrologic models. In this study we use 20 years of streamflow and water quality data, along with a watershed model, to examine sources of stream nutrients and their changes over time in two small streams within the New York City water supply system. We compare sources and trends in stream nitrate and dissolved phosphorus in the urbanized Amawalk watershed with those of the predominantly forested Boyd Corners watershed in the Croton system of reservoirs.
View Article and Find Full Text PDFPLoS One
January 2025
Department of Computer Science, National Textile University, Faisalabad, Pakistan.
Accurate diagnosis of pancreatic cancer using CT scan images is critical for early detection and treatment, potentially saving numerous lives globally. Manual identification of pancreatic tumors by radiologists is challenging and time-consuming due to the complex nature of CT scan images and variations in tumor shape, size, and location of the pancreatic tumor also make it challenging to detect and classify different types of tumors. Thus, to address this challenge we proposed a four-stage framework of computer-aided diagnosis systems.
View Article and Find Full Text PDFWater Res
December 2024
Formerly U.S. Environmental Protection Agency, Office of Research and Development, Center for Public Health and Environmental Assessment, retired, United States.
Estuaries often experience multiple water quality impairments including nitrogen enrichment and elevated fecal pollution. These pollutant sources are often linked and difficult to characterize, especially in multiple use watersheds, hindering the identification of effective mitigation steps. Tillamook Bay (Oregon, USA) has a mixed-use watershed including many potential nutrient and fecal bacteria sources due to agricultural activities, human development, and local wildlife populations.
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