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Quantitative analysis of γ- and δ-lactones in wines using gas chromatography with selective tandem mass spectrometric detection. | LitMetric

Quantitative analysis of γ- and δ-lactones in wines using gas chromatography with selective tandem mass spectrometric detection.

Rapid Commun Mass Spectrom

Dienstleistungszentrum Ländlicher Raum (DLR) Rheinpfalz, Competence Center for Wine Research, Breitenweg 71, D-67435, Neustadt an der Weinstraße, Germany.

Published: December 2013

AI Article Synopsis

  • - Aroma relevant γ- and δ-lactones are key flavor compounds in food, and accurately measuring them is crucial for assessing sensory qualities and food authenticity.
  • - A high-throughput method using head-space solid-phase microextraction and capillary gas chromatography paired with triple stage quadrupole mass spectrometry was evaluated for analysis.
  • - The approach allows for the detection and quantification of γ- and δ-lactones at very low levels (sub-µg/L) in complex wine samples, enhancing reliability in their analysis.

Article Abstract

Rationale: Aroma relevant γ- and δ-lactones are important flavor compounds in various foodstuffs. Their quantitative determination is essential for evaluating food sensory properties as well as food authenticity studies.

Methods: High-throughput head-space solid-phase microextraction as sample preparation, separation by capillary gas chromatography coupled with triple stage quadrupole mass spectrometry has been evaluated as the analytical method.

Results: Monitoring selected reaction mass fragments allowed sub-µg/L quantification of γ- and δ-lactones in complex wine matrices.

Conclusions: Tandem mass spectrometry improves specific detection of γ- and δ-lactones, a prerequisite for reliable quantification at low-µg/L concentration levels in complex wine matrices.

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Source
http://dx.doi.org/10.1002/rcm.6736DOI Listing

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