A quatridentate bis-amide ligand, N,N'-propylenebis(salicylamide) H2pbs, and its transition metal complexes [M(pbs)(H2O)2], where M=Co(II), Ni(II), Cu(II), and Zn(II) have been synthesized and characterized by elemental analysis, UV-Vis, IR, NMR, Mass, EPR, molar conductivity, magnetic moment values and thermal analysis. The NMR spectrum of ligand evidences the E/Z isomerism. All the evidences reveal that the metal ions adopt octahedral geometry with metal:ligand:solvent ratio 1:1:2. The conductivity measurements exhibit that the complexes are non-electrolytes. DNA binding properties of these complexes have been explored by UV-Vis and cyclic voltammetry. The results indicate that these complexes are good intercalators.
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