Trace metal fractionation as a mean to improve on the management of contaminated sediments from runoff water in infiltration basins.

Environ Technol

PRES LUNAM, French Institute of Science and Technology for Transport, Development and Networks (IFSTTAR), Department of Geotechnics, Water and Risks, Centre de Nantes, France.

Published: December 2013

The management of stormwater sediment is a key issue for local authorities due to the pollution load and significant tonnages. In view of reuse, for example for civil engineering, the environmental evaluation of these highly aggregated sediments requires the study of the fractionation and mobility of trace metals. The distribution of trace metals (Cd, Cr, Cu, Ni, Pb, Zn) and their level of lability in three French stormwater sediments was determined using sequential and kinetic extractions (EDTA reagent) associated with mineralogical analysis and scanning electron microscopy observations. Using microanalysis, new data were acquired on the evolution of aggregate state during extractions, and on its significant role in the retention of trace metals. Trace metals were, in particular, observed to be very stable in small aggregates (10-50 microm). Comparison of the two extraction methods revealed that EDTA extraction was not convenient for evaluating the stable fraction of Cr, Ni and Zn. Moreover, the results were relevant for basins presenting similar sources of trace metals, whatever the physicochemical conditions in basins. The results suggest that the management of stormwater sediments could be improved by a better knowledge of metal mobility, as chemical extractions could highlight the localization of the mobile fraction of trace metals. Treatment could be therefore avoided, or specific treatment could be applied to a reduced volume of sediments.

Download full-text PDF

Source
http://dx.doi.org/10.1080/09593330.2012.745619DOI Listing

Publication Analysis

Top Keywords

trace metals
24
basins management
8
management stormwater
8
stormwater sediments
8
trace
7
metals
6
sediments
5
trace metal
4
metal fractionation
4
fractionation improve
4

Similar Publications

Assessment of Long-Term Degradation of Adsorbents for Direct Air Capture by Ozonolysis.

J Phys Chem C Nanomater Interfaces

January 2025

Oak Ridge National Laboratory, Oak Ridge, Tennessee 37830, United States.

Porous adsorbents are a promising class of materials for the direct air capture of CO (DAC). Practical implementation of adsorption-based DAC requires adsorbents that can be used for thousands of adsorption-desorption cycles without significant degradation. We examined the potential degradation of adsorbents by a mechanism that appears to have not been considered previously, namely, ozonolysis by trace levels of ozone from ambient air.

View Article and Find Full Text PDF

Heart failure with preserved ejection fraction (HFpEF) emerges as a singular subclass of heart failure, bereft of specific therapeutic options. Magnesium, an indispensable trace element, is essential to the preservation of cardiac integrity. However, the association between magnesium supplementation and mortality in HFpEF patients remains unclear.

View Article and Find Full Text PDF

Enhanced detection of measurement anomalies in cartridge cases using 3D gray-level co-occurrence matrix.

Forensic Sci Int

January 2025

Department of Forensic Science and Technology, Sichuan Police College, No. 186, Longtouguan Road, Jiangyang District, Luzhou 646000, China; Sichuan Provincial Key Lab of Intelligent Policing, No. 186, Longtouguan Road, Jiangyang District, Luzhou 646000, China. Electronic address:

The firing pin impression left on the base of a cartridge case is a critical analytical feature in forensic science. To address the limitations of traditional manual trace analysis and mitigate the risk of secondary damage to physical evidence, we employ a line laser displacement sensor to capture and analyze three-dimensional (3D) traces of fired cartridge cases. However, when using laser displacement sensors to collect traces from metal cartridge cases, the high curvature and reflectivity of the metal surface can cause specular reflections, potentially leading to measurement anomalies in the firing pin impressions.

View Article and Find Full Text PDF

Visual detection of kanamycin with functionalized Au nanoparticles.

Mikrochim Acta

January 2025

Institute of Chemical Engineering, Guangdong Academy of Sciences, Guangzhou, 510665, People's Republic of China.

A simple and rapid colorimetric detection strategy, based on hydrogen bond identification of 6-thioguanine (6-TG) functionalized Au nanoparticles (AuNPs), is proposed for highly selective and sensitive determination of kanamycin (KA). In this strategy, the hydrogen bond interaction between 6-TG and kanamycin induces AuNPs to agglomerate, with a consequent color change of AuNPs from wine red to purple or even blue. The kanamycin concentrations can be quantified by employing UV-vis spectrophotometer.

View Article and Find Full Text PDF

This research assesses heavy metal contamination within the riparian zone of the Danro River, a tributary of the Ganges River basin in India, particularly impacted by sand mining activities. The study conducted analyses on major and trace elements in soil samples, focusing on those identified as ecologically hazardous by the Water Framework Directive of India. Utilizing a combination of indices (Enrichment Factor, Pollution Load Index, and Index of geo-accumulation) and statistical techniques such as Principal Component Analysis (PCA), the investigation aimed to evaluate contamination severity, ecological risks, and pollution sources.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!