This study describes the synthesis of carboxymethylxylan (CMX) and investigates its suitability as a film for packaging applications. High-purity polymeric xylan was extracted from commercial bleached birch kraft pulp and converted to CMX with three different degrees of substitution (DSs). The water vapor sorption, mechanical, and barrier properties of the films prepared from CMX were tested. Increasing DS of CMX films resulted in an increase in elongation at break and a decrease in tensile strength and Young's modulus. The DS also affected the barrier properties of the films. CMX films with higher DS showed improved (reduced) oxygen permeability (OP), and the water vapor permeability (WVP) increased with DS. It was demonstrated that the carboxymethylation of xylan recovered from industrial side-streams and its conversion to packaging films could be a viable option to valorize xylan.
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http://dx.doi.org/10.1016/j.carbpol.2013.03.048 | DOI Listing |
J Phys Chem Lett
January 2025
College of Electronic and Optical Engineering & College of Flexible Electronics (Future Technology), State Key Laboratory of Organic Electronics and Information Displays, Nanjing University of Posts and Telecommunications, Nanjing, Jiangsu 210023, P.R. China.
Heat dissipation has become a critical challenge in modern electronics, driving the need for a revolution in thermal management strategies beyond traditional packaging materials, thermal interface materials, and heat sinks. Cubic boron arsenide (c-BAs) offers a promising solution, thanks to its combination of high thermal conductivity and high ambipolar mobility, making it highly suitable for applications in both electronic devices and thermal management. However, challenges remain, particularly in the large-scale synthesis of a high-quality material and the tuning of its physical properties.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
College of Food Science and Engineering, Wuhan Polytechnic University, Wuhan 430023, China; Hubei Industrial Technology Research Institute of Jingchu Special Foods, Jingzhou 434000, China. Electronic address:
In this work, a nanocomposite film, designated as CS/PA, was fabricated by integrating chitosan (CS), porphyrinic porous coordination network (PCN), and silver nanoparticles (AgNPs). PCN modified AgNPs was denoted as PCN-AgNPs (PA). The synthesis of PA was verified through transmission electron microscope, Zeta potential, hydrated particle size, element mapping.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
Division of Biotechnology, Karunya Institute of Technology and Sciences, Coimbatore, Tamil Nadu 641114, India. Electronic address:
Conventional food packaging is creating a significant cause of environmental hazards, posing challenges in disposal and recycling. Lignocellulose fibers possess remarkable biodegradable properties and can be modified or blended with other polymers. Thus, using lignocellulose biocomposite films derived from barley, a renewable source can mitigate and potentially transform into sustainable, innovative packaging material in the food sectors.
View Article and Find Full Text PDFFood Chem
January 2025
Laboratory of Agricultural and Food Biophysics, Institute of Biophysics, College of Science, Northwest A&F University, Yangling, Shaanxi 712100, China; Laboratory of Muscle Biology and Meat Science, National Beef Cattle Improvement Center, College of Animal Science and Technology, Northwest A&F University, Yangling, Shaanxi 712100, China; Laboratory of Meat Quality Analysis and Products Development, Ningxia Xihaigu Institute of High-end Cattle Industry, Haiyuan, Ningxia 755299, China. Electronic address:
Multifunctional pH-responsive films were fabricated via layer-by-layer deposition of gelatin, chitosan, and carboxymethyl cellulose (CMC), incorporating selenium nanoparticles (SeNPs) and beetroot extract (BTE), to monitor and preserve beef freshness. SeNPs were synthesized and characterized via various techniques. BTE exhibited promising functional properties, and films demonstrated a significant color transition from red to yellow across pH 2-14.
View Article and Find Full Text PDFFood Chem
January 2025
College of Food Science and Engineering, Northwest A&F University, Yangling, Shaanxi Province 712100, China. Electronic address:
This work pioneered an innovative visible light-powered, self-cascading peroxide antimicrobial packaging system (RPFe-CS), featuring a photodynamic enhancement effect achieved through the demand-oriented design of riboflavin sodium phosphate and Fe coordination complexes (RPFe) fillers with photodynamic and peroxidase activities, and the ingenious selection of slightly acidic chitosan (CS) film matrix. In this system, the photo-responsive properties of RPFe particles not only generate the •O, •OH, and O required for photodynamic sterilization, but also the produced HO serves as a necessary substrate for peroxidase to exert its bactericidal effect, endowing the packaging system with a "self-production and self-marketing" cascade process. The RPFe-CS film achieved efficient eradication to bacteria and fungi reaching up to 99.
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