Bimetallic combinations for dehalogenative metalation involving organic compounds.

Chem Rev

Equipe Chimie et Photonique Moléculaires, Institut des Sciences Chimiques de Rennes, UMR 6226 CNRS-Université de Rennes 1, Bâtiment 10A, Case 1003, Campus de Beaulieu, Avenue du Général Leclerc, 35042 Rennes Cédex, France.

Published: January 2014

Download full-text PDF

Source
http://dx.doi.org/10.1021/cr400367pDOI Listing

Publication Analysis

Top Keywords

bimetallic combinations
4
combinations dehalogenative
4
dehalogenative metalation
4
metalation involving
4
involving organic
4
organic compounds
4
bimetallic
1
dehalogenative
1
metalation
1
involving
1

Similar Publications

Carbon-doped bimetallic oxide nanoflakes for simultaneous electrochemical analysis of ascorbic acid, uric acid, and acetaminophen in sweat.

Anal Methods

January 2025

Shanghai Key Laboratory of Functional Materials Chemistry, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai, 200237, People's Republic of China.

Non-invasive continuous detection using tears or sweat as substitutes for blood samples has become an emerging method for real-time monitoring of human health. However, its development is limited by the low sample volume and low level of analytes. The simultaneous determination of multi-analytes with highly sensitive electrochemical sensing platforms has undoubtedly resulted in breakthrough innovations.

View Article and Find Full Text PDF

Ultralight flexible 3D nickel micromesh decorated with NiCoP for high stability alkaline zinc batteries.

Nanoscale

January 2025

National Engineering Research Center for High-Efficiency Grinding, State Key Laboratory of Advanced Design and Manufacturing Technology for Vehicle, College of Mechanical and Vehicle Engineering, Hunan University, Changsha 410082, China.

Rechargeable alkaline zinc batteries are emerging as promising candidates for next-generation energy storage systems, owing to their affordability, eco-friendliness and high energy density. However, their widespread application is hindered by stability challenges, particularly in alkaline environments, due to cathode corrosion and deformation, as well as dendrite formation and unwanted side reactions at the Zn anode. To address these issues, we successfully developed a 3D nickel micromesh-supported NiCoP (3D NM@NiCoP) electrode.

View Article and Find Full Text PDF

Cancer remains a leading cause of mortality, with aggressive, treatment-resistant tumors posing significant challenges. Current combination therapies and imaging approaches often fail due to disparate pharmacokinetics and difficulties correlating drug delivery with therapeutic response. In this study, we developed radionuclide-activatable theranostic nanoparticles (NPs) comprising folate receptor-targeted bimetallic organo-nanoparticles (Gd-Ti-FA-TA NPs).

View Article and Find Full Text PDF

In situ decoration of AuPd nanoparticles on MOF derived ZnO for ultra-high response and low detection limit trimethylamine detection.

Anal Chim Acta

February 2025

School of Physics and Electronic Information Engineering, Henan Polytechnic University, Jiaozuo, 454003, China. Electronic address:

Background: Trimethylamine (TMA) is a colorless, volatile gas with a strong irritating odor. Prolonged exposure to a certain amount of TMA can cause symptoms such as dizziness, nausea and difficulty breathing, and may even be life-threatening. Therefore, effective detection of TMA is crucial.

View Article and Find Full Text PDF

CO driven tunable syngas synthesis via CO photoreduction using a novel NiCo bimetallic metal-organic frameworks.

J Colloid Interface Sci

January 2025

School of Chemistry, Sun Yat-sen University, Guangzhou 510275, Guangdong, China. Electronic address:

Syngas has important industrial applications, and converting CO to CO is critical for syngas production. Metal-organic frameworks (MOFs) have demonstrated significant potential in photocatalytic syngas conversion, although the impact of catalytic reactions on tunable H/CO ratios remains unclear. Herein, we present a novel bimetallic NiCo-MOF catalyst, NiCo, exhibiting high catalytic activity in syngas conversion due to the CO product self-driven effect.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!