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The β-nitration reaction carried out on the corrole macrocycle has been shown to be extremely regioselective, although the reduced symmetry of the macrocycle could potentially lead to a huge number of possible regioisomers. We recently reported that the careful use of AgNO/NaNO as a nitrating system enabled the achievement in good yields of mono- and dinitro-derivatives on both corrole free base and its copper complex, proving to be an efficient and cost-effective method. In this work, we present a detailed study of the scope of this method using TtBuCorrH as a model corrole. A further increase of the oxidant pushes the nitration up to the functionalization of three β-pyrrolic positions, although concomitant decomposition of the macrocycle is also observed. The application of the proven nitration method with a five-fold excess of both silver and sodium nitrites with respect to corrole, afforded the 2,3,17-(NO)-TtBuPCorrCu as the main product, in 25% yield, together with traces of another compound identified by X-ray crystallographic analysis as the 3,8,17-(NO)-TtBuPCorrCu isomer. In light of these recent results, we also reinvestigated the characterization of the nitration products obtained from bis-substitution reactions, allowing among others the identification of the copper 3,8-(NO) corrolate.
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http://dx.doi.org/10.1142/S1088424613500120 | DOI Listing |
Environ Geochem Health
December 2024
Department of Chemistry, Kwame Nkrumah University of Science and Technology, Kumasi, Ghana.
Cocoa-growing areas in Ghana have experienced a rise in mining activities affecting cocoa cultivation and increased concentrations of potentially toxic metals in the soil, which can accumulate in cocoa beans. This study evaluated potential toxic metal contamination in cocoa beans and soils from cocoa farms in mining and non-mining areas in Ghana. We used X-ray fluorescence and an ICP-MS to determine metal concentrations, and a Zeeman mercury analyzer to determine mercury.
View Article and Find Full Text PDFEnviron Geochem Health
December 2024
Da Lat Nuclear Research Institute, 01 Nguyen Tu Luc, Da Lat, Lam Dong, 670000, Vietnam.
This study investigates the quantities of Rare Earth Elements (REEs) and Potentially Toxic Elements (PTEs) in Dong Nai Province's surface soils. Atomic Absorption Spectrometry (AAS) and Instrumental Neutron Activation Analysis (INAA) were used to determine element concentrations. To validate the concentration results, established reference materials (NIST 2711 and IAEA Soil-7) were used.
View Article and Find Full Text PDFInorg Chem
December 2024
College of Energy Materials and Chemistry, Inner Mongolia University, Hohhot 010021, China.
Ligand-stabilized metal nanoclusters with atomic precision are considered to be promising materials in the field of light-emitting and harvesting. Among these, nanoclusters with thermally activated delayed fluorescence (TADF) properties are highly sought after. While several gold and silver nanoclusters with TADF properties have been reported in recent years, research on copper counterparts has significantly lagged behind.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
December 2024
Department of Polymeric Materials and Engineering, School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, China. Electronic address:
High copper levels pose a risk to environmental and human health due to their toxicity and widespread industrial application, in which abnormal copper levels are associated with various diseases both in neurodegenerative diseases and plant growth. Thus, a turn-on fluorescent probe BBYD-Cu, based on donor-acceptor type structure, was designed and synthesized with easy preparations. BBYD-Cu can specifically recognized Cu by 2-picolinic ester group, then released the fluorophore to enhance the fluorescent signals.
View Article and Find Full Text PDFJ Colloid Interface Sci
December 2024
Pingshan Translational Medicine Center, Shenzhen Bay Laboratory, Shenzhen 518118, China. Electronic address:
Copper-based materials are promising for formaldehyde oxidation to produce hydrogen but suffer from degradation caused by soluble copper ions in alkaline electrolytes. In this report, a novel CuPd/CC alloy electrocatalyst is developed to address this issue. The catalyst drives formaldehyde oxidation at 0.
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