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Combining Two Methods of Sequence Definition in a Convergent Approach: Scalable Synthesis of Highly Defined and Multifunctionalized Macromolecules.
Chemistry
October 2017
Institute of Organic Chemistry, Karlsruhe Institute of Technology (KIT), Straße am Forum 7, 76131, Karlsruhe, Germany.
The straightforward convergent synthesis of sequence-defined and multifunctionalized macromolecules is described herein. The first combination of two efficient approaches for the synthesis of sequence-defined macromolecules is reported: thiolactone chemistry and the Passerini three-component reaction (P-3CR). The thiolactone moiety was used as protecting group for the thiol, allowing the synthesis of a library of sequence-defined α,ω-functionalized building blocks.
View Article and Find Full Text PDFMultifunctionalized sequence-defined oligomers from a single building block.
Angew Chem Int Ed Engl
December 2013
Polymer Chemistry Research Group, Department of Organic Chemistry, Ghent University, Krijgslaan 281, S4, 9000 Gent (Belgium).
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