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Coordinating chiral ionic liquids. | LitMetric

Coordinating chiral ionic liquids.

Org Biomol Chem

Institute of Applied Synthetic Chemistry, Vienna University of Technology, 1060 Vienna, Austria.

Published: December 2013

AI Article Synopsis

  • A new method was created to synthesize chiral ionic liquids using readily available amino alcohols.
  • These chiral ionic liquids were effective as catalysts in the asymmetric alkylation of aldehydes.
  • The process achieved high enantioselectivity, reaching up to 91% ee.

Article Abstract

A practical synthesis of novel coordinating chiral ionic liquids with an amino alcohol structural motif was developed starting from commercially available amino alcohols. These basic chiral ionic liquids could be successfully applied as catalysts in the asymmetric alkylation of aldehydes and gave high enantioselectivities of up to 91% ee.

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Source
http://dx.doi.org/10.1039/c3ob41635fDOI Listing

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