This paper reports on the effect of concentration of Eu(3+) ions in K2O-Nb2O5-SiO2-Eu2O3 (KNbSiEu) glasses prepared by the melt quenching technique. By using the Judd-Ofelt (JO) theory, the intensity parameters Ωλ (λ=2, 4, 6) have been determined from the absorption and emission spectra of Eu(3+) ions under different constraints. The radiative properties of some of the excited states of Eu(3+) ions have been calculated. The decay curves of (5)D0 level exhibited single exponential for all the Eu(3+) ions concentrations. From these results, it is suggested that the strong red emission at 616 nm corresponding to the (5)D0→(7)F2 transition could be used for the development of optical display devices.
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http://dx.doi.org/10.1016/j.saa.2013.09.094 | DOI Listing |
Mikrochim Acta
January 2025
Key Laboratory of Environmental Remediation and Ecological Health, Ministry of Education, College of Environmental and Resource Sciences, Zhejiang University, Hangzhou, 310058, China.
A sensitized dual-response ratiometric fluorescent sensor integrated smartphone platform for accurate discrimination and detection of tetracycline (TC) homologues was fabricated based on N-CDs-Eu complex. In the sensing system, N-CDs act as a sensitizer of Eu and significantly enhance the fluorescence of TC-Eu complex approximate 40-fold owing to the synergistic effect of antenna effect (AE) and fluorescence resonance energy transfer (FRET). A paper sensor integrated with a smartphone platform is further fabricated for on-site measurement of TC.
View Article and Find Full Text PDFJ Fluoresc
January 2025
Department of Physics, R. T. M. Nagpur University, 440033, Nagpur, India.
The preparation of new phosphor with outstanding luminescent properties for white light-emitting diodes (WLEDs) is consistently a challenging. Here in the present study, A novel white-emitting chloropatite phosphor Ca(PO)Cl:Eu was synthesized via the pechini sol gel synthesis with citric acid and polyethylene glycol (PEG) acid as a fuel at 850 °C systematically investigating the impact of doping concentration and synthesis temperature on both photoluminescence properties and crystal phase. The structural characteristics and crystalline nature of the prepared sample were investigated by using X-ray diffraction (XRD) patterns and Fourier transform infrared (FT-IR) spectra.
View Article and Find Full Text PDFMikrochim Acta
January 2025
Department of Chemistry, Sardar Vallabhbhai National Institute of Technology, Surat, Gujarat, 395 007, India.
A fluorescence "turn-off-on" nanoprobe is designed by using europium-doped strontium molybdate perovskite quantum dots (Eu:SMO PQDs) for the sequential detection of hypoxanthine (Hx) and Fe. The Eu:SMO PQDs were prepared by the sol-gel method using Sr(NO), (NH)MoO.4HO, and Eu(OCOCH) as precursors.
View Article and Find Full Text PDFMolecules
December 2024
Department of Science and Humanities, School of Engineering and Technology, CHRIST University, Bangalore 560029, Karnataka, India.
Using the solid-state reaction technique, varied YSiO phosphors activated by europium (Eu) ions at varied concentrations were made at calcination temperatures of 1000 °C and 1250 °C during sintering in an air environment. The XRD technique identified the monoclinic structure, and the FTIR technique was used to analyze the generated phosphors. Photoluminescence emission and excitation patterns were measured using varying concentrations of Eu ions.
View Article and Find Full Text PDFAdv Sci (Weinh)
January 2025
Yunnan Key Laboratory of Electromagnetic Materials and Devices, National Center for International Research on Photoelectric and Energy Materials, School of Materials and Energy, Yunnan University, Kunming, 650091, China.
Far-red phosphors have emerged as a desirable research hotspot owing to their critical role in promoting plant growth. Especially, Eu ions typically present the D→F (J = 0, 1, 2, 3, 4) transitions, which overlap with the far-red light required for plant photosynthesis. However, achieving high-efficiency far-red emission of Eu remains challenging due to weak D→F transition and concentration quenching.
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