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Experimental and kinetic modeling study of oxidative degradation of benzene and phenol in supercritical water.
J Environ Manage
January 2025
Shaanxi Key Laboratory of New Transportation Energy and Automotive Energy Saving, School of Energy and Electrical Engineering, Chang'an University, Xi'an, Shaanxi, 710064, PR China.
Benzene and phenol are representative aromatic compounds existing commonly in wastewater. The kinetics of oxidative degradation of benzene and phenol in supercritical water have been investigated in a flow reactor at 823 K and 250 atm, with the excess oxygen ratio ranging from 0.5 to 2.
View Article and Find Full Text PDFEnzymatic Interesterification of Cold-Pressed Maqui ( (Mol.) Stuntz) Seed Oil and Belly Oil from Rainbow Trout () Through Supercritical CO.
Mar Drugs
December 2024
Department of Food Technology, Marine Research Institute (CSIC), Eduardo Cabello 6, 36208 Vigo, Spain.
A new antioxidant lipid (AL) was synthesized from rainbow trout () belly oil and cold-pressed maqui (CPM) ( (Mol.) Stuntz) seed oil via enzymatic interesterification using in supercritical CO medium. A Box-Behnken design with 15 experiments was employed, with the independent variables being the following: belly oil/CPM oil ratio (10/90, 50/50, and 90/10, /), supercritical CO temperature (40.
View Article and Find Full Text PDFProcesses of Obtaining Nanostructured Materialswith a Hierarchical Porous Structure on the Example of Alginate Aerogels.
Gels
December 2024
Department of Chemical and Pharmaceutical Engineering, Mendeleev University of Chemical Technology of Russia, Miusskaya pl. 9, 125047 Moscow, Russia.
Currently, materials with specific, strictly defined functional properties are becoming increasingly important. A promising strategy for achieving these properties involves developing methods that facilitate the formation of hierarchical porous materials that combine micro-, meso-, and macropores in their structure. Macropores facilitate effective mass transfer of substances to the meso- and micropores, where further adsorption or reaction processes can occur.
View Article and Find Full Text PDFSupercritical CO coupled with water washing to enhance the removal of chlorine in MSWI fly ash together with its carbon sequestration function.
Waste Manag
December 2024
School of Chemistry and Life Resources, Renmin University of China, No. 59 Zhongguancun Street, Beijing 100872, China.
The high chlorine content in municipal solid waste incineration (MSWI) fly ash is a key factor restricting its treatment and disposal. In this study, a new treatment method was proposed to enhance the deep dechlorination of fly ash by coupling supercritical CO (SC) treatment with water washing. Simultaneously the alkaline compounds in fly ash can fix CO and achieve CO credits.
View Article and Find Full Text PDFControllable reconstruction of lignified biomass with molecular scissors to form carbon frameworks for highly stable Li metal batteries.
Chem Sci
December 2024
Institutes of Physical Science and Information Technology, Key Laboratory of Structure and Functional Regulation of Hybrid Material (Ministry of Education), Anhui University Hefei 230601 China
Lithium metal batteries (LMBs) promise high-energy-density storage but face safety issues due to dendrite-induced lithium deposition, irreversible electrolyte consumption, and large volume changes, which hinder their practical applications. To address these issues, tuning lithium deposition by structuring a host for the lithium metal anode has been recognized as an efficient method. Herein, we report a supercritical water molecular scissor-controlled strategy to form a carbon framework derived from biomass wood.
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