Acoustic measurements provide convenient non-invasive means for the characterisation of materials. We show here for the first time how a commercial impedance tube can be used to provide accurate measurements of the velocity and attenuation of acoustic waves in liquid foams, as well as their effective "acoustic" density, over the 0.5-6kHz frequency range. We demonstrate this using two types of liquid foams: a commercial shaving foam and "home-made" foams with well-controlled physico-chemical and structural properties. The sound velocity in the latter foams is found to be independent of the bubble size distribution and is very well described by Wood's law. This implies that the impedance technique may be a convenient way to measure in situ the density of liquid foams. Important questions remain concerning the acoustic attenuation, which is found to be influenced in a currently unpredictible manner by the physico-chemical composition and the bubble size distribution of the characterised foams. We confirm differences in sound velocities in the two types of foams (having the same structural properties) which suggests that the physico-chemical composition of liquid foams has a non-negligible effect on their acoustic properties.
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http://dx.doi.org/10.1140/epje/i2013-13113-1 | DOI Listing |
Environ Sci Technol
January 2025
Department of Civil and Environmental Engineering, Clarkson University, Potsdam, New York 13699, United States.
The nonthermal destruction of aqueous film-forming foam (AFFF) stockpiles, one of the major culprits responsible for water and soil contamination by per- and polyfluoroalkyl substances (PFAS), is extremely challenging because of the coexistence of mixed recalcitrant PFAS and complicated organic matrices at extremely high concentrations. To date, the complete defluorination of undiluted AFFF at ambient conditions has not been demonstrated. This study reports a novel piezoelectric ball milling approach for treating AFFF with a total organic fluorine concentration of 9080 mg/L and total organic carbon of 234 g/L.
View Article and Find Full Text PDFPolymers (Basel)
December 2024
Enikolopov Institute of Synthetic Polymeric Materials of Russian Academy of Sciences (ISPM RAS), Profsoyuznaya Str. 70, 117393 Moscow, Russia.
To achieve the actuation of silicone-based foamed composites, a liquid-gas phase transition of the liquid captured in its pores is employed. The uncertainty of key parameters for a single or sequential open-air performance of such soft actuators limits their application. To define the main characteristics of the composites, in this work, two functions of the liquid there were separated: the pore-forming agent (FPA) and working liquid (WL).
View Article and Find Full Text PDFMolecules
December 2024
College of Agriculture and Bioengineering, Heze University, Heze 274000, China.
This study optimized the process of extracting protein from black garlic using an alkaline dissolution and acid precipitation method through response surface methodology. The optimal extraction conditions were determined as a solid-to-liquid ratio of 1:50, an extraction time of 100 min, an extraction temperature of 30 °C, and an alkaline extraction pH of 9.0.
View Article and Find Full Text PDFEnviron Int
January 2025
Département de Chimie, Université de Montréal, Montreal, QC, Canada. Electronic address:
This study investigated the occurrence of perfluoroalkyl and polyfluoroalkyl substances (PFAS), including anionic, cationic, and zwitterionic compounds, in drinking water. Between 2021-2023, an expanded list of 76 target PFAS was screened in tap water samples mainly from Canada, but also including tap water samples from the Eastern United States, Mexico, South America (Argentina), the Caribbean (Dominican Republic, Cuba), Africa (Algeria, Cameroon, Central African Republic, Morocco, Rwanda, Tunisia), Europe (France, Greece, Italy, Spain, and the United Kingdom) and Asia (Japan, Vietnam, Iran, and Türkiye). An additional ∼ 200 suspect-target PFAS were screened using high-resolution Orbitrap mass spectrometry.
View Article and Find Full Text PDFSci Rep
January 2025
Key Laboratory of Gas and Fire Control for Mines, Ministry of Education, Xuzhou, 221116, China.
Confined space fires could easily cause serious casualties and property damage, and foam is an effective means of preventing confined space fires. The existing foam generator does not have both momentum and foam expansion rate (FER) and is poorly suited to confined spaces. In order to develop a foam generator suitable for confined space fire protection, an in-depth analysis of the physical foaming characteristics of self-suction foam is required, and the structure of the foam generator is optimized accordingly.
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