In this article, we demonstrate for the first time that ultrathin graphitic carbon nitride nanosheets (g-C3N4) possess peroxidase activity. Fe doping of the nanosheets leads to peroxidase mimetics with greatly enhanced catalytic performance and the mechanism involved is proposed. We further demonstrate the novel use of such Fe-g-C3N4 as a cheap nanosensor for simple, rapid, highly selective and sensitive optical detection of glucose with a pretty low detection limit of 0.5 μM.
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http://dx.doi.org/10.1039/c3nr03693f | DOI Listing |
Environ Res
December 2024
College of Materials Science and Engineering, Fuzhou University, Fuzhou, 350116, PR China. Electronic address:
This work developed a novel oxidized hierarchical porous carbon (OHPC) with vesicule-like ultrathin graphitic walls via a method of air oxidation and used as an efficient adsorbent for Congo red (CR) and Malachite green (MG) removal. Results show that the OHPC2 oxidized at 400 °C possesses three-dimensional hierarchical pores with vesicule-like ultrathin graphitic walls. The prepared OHPC2 not only has a large specific surface area of 1020 m g with a high pore volume, but also has abundant oxygen-containing functional groups.
View Article and Find Full Text PDFBiomed Mater
January 2025
Antimicrobial Resistance Research Center, Institute of Immunology and Infectious Diseases, Iran University of Medical Sciences, Tehran, Iran.
Different morphologies of graphitic carbon nitride (g-CN), including bulk g-CN(B-CN), ultrathin nanosheet g-CN(N-CN), and porous g-CN(P-CN) were synthesized through a facile one-step approach. They were then employed as efficient photocatalysts under visible light to degrade methylene blue and deactivate() and() bacteria. The synthesized powders were characterized using various industry standard techniques and field emission scanning electron microscopy (SEM) analysis successfully represented the various morphologies of g-CN.
View Article and Find Full Text PDFACS Nano
December 2024
Beijing Key Laboratory of Energy Conversion and Storage Materials, College of Chemistry, Beijing Normal University, Beijing 100875, P. R. China.
To achieve high accuracy and effectiveness in sensing and modulating neural activity, efficient charge-transfer biointerfaces and a high spatiotemporal resolution are required. Ultrathin bioelectrode arrays exhibiting mechanical compliance with biological tissues offer such biointerfaces. However, their thinness often leads to a lack of mechano-electrical stability or sufficiently high electrochemical capacitance, thus deteriorating their overall performance.
View Article and Find Full Text PDFAdv Mater
December 2024
Institute of Physical Chemistry, Friedrich Schiller University Jena, 07743, Jena, Germany.
Due to their ultra-high sensitivity, solution-gated graphene-based field-effect transistors (SG-GFET) have been proposed for applications in bio-sensing. However, challenges regarding the functionalization of GFETs have prevented their applications in clinical diagnostics so far. Here GFET sensors based on van der Waals (vdW) heterostructures of single-layer graphene layered with a molecular ≈1 nm thick carbon nanomembrane (CNM) are presented.
View Article and Find Full Text PDFLangmuir
October 2024
School of Physics and Optoelectronic Engineering, Guangdong University of Technology, HEMC, Guangzhou 510006, China.
Graphitic carbon nitride (g-CN) is a fascinating material with potential applications in photocatalysis due to its good chemical stability, high thermal stability, and relative ease of synthesis. In this work, ultrathin g-CN is constructed using a hybridized method, which combines the advantages of thermal and liquid-phase stripping methods. This sample can improve performance in degrading organic pollutants several times, and the highest enhancement efficiency occurs in an alkaline environment.
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