Z-Selective ring opening of vinyl oxetanes with dialkyl dithiophosphate nucleophiles.

Chem Commun (Camb)

Department of Chemistry and Biochemistry, The University of Arizona, 1306 East University Blvd., Tucson, Arizona 85721, USA.

Published: November 2013

Dialkyl dithiophosphates selectively ring open vinyl oxetanes in excellent yields under mild reaction conditions to form useful allylic thiophosphate products with high Z-selectivity.

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Source
http://dx.doi.org/10.1039/c3cc46660dDOI Listing

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