In this Letter, for the first time, we demonstrated the preparation of a highly efficient electrocatalyst, spinel CuCo2O4 nanoparticles supported on N-doped reduced graphene oxide (CuCo2O4/N-rGO), for an oxygen reduction reaction (ORR) under alkaline media. The hybrid exhibits higher ORR catalytic activity than CuCo2O4 or N-rGO alone, the physical mixture of CuCo2O4 nanoparticles and N-rGO, and Co3O4/N-rGO. Moreover, such a hybrid affords superior durability to the commercial Pt/C catalyst.
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Sci Rep
August 2024
Physics Department, Faculty of Science, Amran University, Amran, Yemen.
This study investigates the development of novel nanocomposite films based on a blend of polyethylene oxide (PEO) and polyvinyl alcohol (PVA) loaded with varying weight percentages of copper cobaltite nanoparticles (CuCoO NPs). The primary objective was to fabricate these nanocomposites using a solution casting technique and explore the influence of CuCoO content on their structural, optical, electrical, and dielectric properties. Spinel-type CuCoO NPs were synthesized via the hydrothermal method and incorporated into the PEO/PVA blend.
View Article and Find Full Text PDFEnviron Res
June 2024
Department of Physics, Christian College, Chengannur, Kerala, India, 689122; University of Kerala, Thiruvananthapuram, Kerala, India. Electronic address:
There has been a growing interest in the design and development of graphene based composite materials with superior performances for environmental catalytic applications. But in most of the studies the synthesis conditions require elevated temperatures and expensive working setups (high temperature furnaces, autoclaves, inert atmosphere conditions etc.).
View Article and Find Full Text PDFAnal Bioanal Chem
January 2024
Guizhou Engineering Laboratory for Synthetic Drugs (Ministry of Education of Guizhou Province), College of Pharmacy, Guizhou University, Guiyang, 550025, China.
As a central neurotransmitter, DA (dopamine) plays a vital part in human metabolism, and its accurate detection is of great significance in disease diagnosis. In this work, we used Cu/Co bimetallic metal-organic frameworks (MOFs) as templates and gold nanoparticles (AuNPs) to construct novel nanocomposite coral-like CuCoO@AuNPs with strong peroxidase activity and electrochemical response. The coral-like CuCoO@AuNPs showed excellent peroxidase activity, and the K value was as low as 0.
View Article and Find Full Text PDFAnal Chem
May 2022
Collaborative Innovation Center for Green Chemical Manufacturing and Accurate Detection, School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, PR China.
The evolution of electrochemiluminescence (ECL) emission amplified by coreaction accelerator in near-infrared (NIR) area has been overwhelmingly anticipated for ultrasensitive detection of disease biomarkers. Herein, the hollow double-shell CuCoO@CuO (HDS-CuCoO@CuO) heterostructures were conveniently prepared and utilized as an attractive coreaction accelerator to improve the NIR ECL performance of gold nanoclusters (AuNCs) for the first time. Benefiting from perfect-matched lattice spacing, unique CuO nanoparticles (NPs) were formed in situ on the layered-hollow CuCoO nanospheres (NSs) to obtain HDS-CuCoO@CuO heterostructures.
View Article and Find Full Text PDFInorg Chem
December 2021
Key Laboratory of Polymer Materials of Gansu Province, Key Laboratory of Eco-functional Polymer Materials of the Ministry of Education, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, Gansu 730070, China.
Exploring effective electrocatalysts for oxygen evolution reaction (OER) is a crucial requirement of many energy storage and transformation systems, involving fuel cells, water electrolysis, and metal-air batteries. Transition-metal oxides (TMOs) have attracted much attention to OER catalysts because of their earth abundance, tunable electronic properties, and so forth. Defect engineering is a general and the most important strategy to tune the electronic structure and control size, and thus improve their intrinsic activities.
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