Hunt for geometric phase effects in H + HD → HD(v', j') + H.

J Chem Phys

Department of Chemistry, Stanford University, Stanford, California 94305-5080, USA.

Published: October 2013

An attempt has been made to measure the theoretically predicted manifestation of a geometric phase in the differential cross section for the H + HD → HD(v' = 2, j' = 5) + H reaction at a center-of-mass collision energy of 1.44 eV (33.2 kcal∕mol). Minute oscillatory differences between calculated differential cross sections that take into account and ignore the effect of geometric phase have proven to be beyond our experimental resolution in spite of the collection of more than 44,000 ions.

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http://dx.doi.org/10.1063/1.4821601DOI Listing

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