The title compound, C17H26Br2, was synthesized from β-himachalene (3,5,5,9-tetra-methyl-2,4a,5,6,7,8-hexa-hydro-1H-benzo-cyclo-heptene), which was isolated from the essential oil of the Atlas cedar (Cedrus Atlantica). The asymmetric unit contains two independent mol-ecules with similar conformations. Each mol-ecule is built up from fused six- and seven-membered rings and two appended three-membered rings. In both mol-ecules, the six-membered ring has a screw boat conformation, whereas the seven-membered ring displays a boat conformation. No specific inter-molecular inter-actions were discerned in the crystal packing.
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http://dx.doi.org/10.1107/S160053681301903X | DOI Listing |
Org Biomol Chem
December 2024
Department of Chemistry, IIT Bombay, Powai-400076, Mumbai, India.
We report the synthesis, characterization, and studies of novel 3-pyrrolyl BODIPY-based Schiff base products 3-6 and 3-pyrrolyl BODIPY-based benzo[]thiazol-2-yl derivatives 7-8. The Schiff base compounds 3-6 were synthesized condensation of α-formyl 3-pyrrolyl BODIPY with various amine derivatives, while the Knoevenagel condensation products 7-8 were obtained by reacting α-formyl 3-pyrrolyl BODIPY with 2-(benzo[]thiazol-2-yl) acetonitrile and bis(benzo[]thiazol-2-yl) methane, respectively. The compounds were thoroughly characterized by using HR-MS, 1D and 2D NMR spectroscopy, and X-ray crystallography for two compounds.
View Article and Find Full Text PDFJ Am Chem Soc
December 2024
Department of Chemistry, Aarhus University, DK-8000 Aarhus C, Denmark.
A mechanistic investigation into the novel combination of the -halogen effect with enantioselective aminocatalysis unravels the mechanistic intricacies of [6 + 4] and [10 + 6] higher-order cycloadditions and the succeeding new Favorskii-like rearrangements. By introducing the OTf-group into the tropone framework, it can serve both as an activator for the cycloaddition and as a proficient leaving group within the corresponding cycloadduct, thus enabling unprecedented ring-contracting Favorskii-like rearrangements. Integrating the -OTf group creates an electron-deficient 6π-component leveraging the -halogen effect by enhancing the polarization and introducing new strategic interaction points.
View Article and Find Full Text PDFInorg Chem
December 2024
Equipe de Synthèse pour l'Analyse, Université de Strasbourg, CNRS, IPHC UMR 7178, Strasbourg F-67 087, France.
J Am Soc Mass Spectrom
December 2024
Department of Chemistry, Bagley Hall, University of Washington, Box 351700, Seattle, Washington 98195-1700, United States.
ACS Macro Lett
November 2024
Institute of Chemical Materials, China Academy of Engineering Physics, Mianyang 621900, China.
Modulating the coefficient of thermal expansion (CTE) and realizing low or negative thermal expansion (NTE) for epoxy polymers are challenging issues. In this study, we developed an effective strategy to prepare epoxy polymers with an NTE performance. A novel motif DBCOD-NH based on the dibenzocyclooctadiene (DBCOD) was designed, synthesized, and utilized as a curing agent for several commercial epoxy resins.
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