AI Article Synopsis

  • Rayleigh anomalies (RAs) in metal nanogratings provide high bulk refractive-index sensitivity based on grating period, but surface sensitivity needs further examination for practical sensing applications.
  • When evaluating local refractive-index changes, surface sensitivity can decrease significantly—up to 100 times lower than bulk sensitivity.
  • This loss in surface sensitivity is linked to plasmonic effects rather than changes in wavelength of the RAs and suggests that with increasing overlay thickness, surface sensitivity could approach the bulk RA sensitivity, revealing its maximum potential for sensing applications.

Article Abstract

Sensing schemes based on Rayleigh anomalies (RAs) in metal nanogratings exhibit an impressive bulk refractive-index sensitivity determined solely by the grating period. However, the surface sensitivity (which is a key figure of merit for label-free chemical and biological sensing) needs to be carefully investigated to assess the actual applicability of this technological platform. In this paper, we explore the sensitivity of RAs in metal nanogratings when local refractive-index changes are considered. Our studies reveal that the surface sensitivity deteriorates up to two orders of magnitude by comparison with the corresponding bulk value; interestingly, this residual sensitivity is not attributable to the wavelength shift of the RAs, which are completely insensitive to local refractive-index changes, but rather to a strictly connected plasmonic effect. Our analysis for increasing overlay thickness reveals an ultimate surface sensitivity that approaches the RA bulk value, which turns out to be the upper-limit of grating-assisted surface-plasmon-polariton sensitivities.

Download full-text PDF

Source
http://dx.doi.org/10.1364/OE.21.023531DOI Listing

Publication Analysis

Top Keywords

surface sensitivity
16
rayleigh anomalies
8
ras metal
8
metal nanogratings
8
local refractive-index
8
refractive-index changes
8
sensitivity
6
surface
4
sensitivity rayleigh
4
anomalies metallic
4

Similar Publications

Land Surface Temperature (LST) is widely recognized as a sensitive indicator of climate change, and it plays a significant role in ecological research. The ERA5-Land LST dataset, developed and managed by the European Centre for Medium-Range Weather Forecasts (ECMWF), is extensively used for global or regional LST studies. However, its fine-scale application is limited by its low spatial resolution.

View Article and Find Full Text PDF

Molecular basis of proton sensing by G protein-coupled receptors.

Cell

December 2024

Department of Pharmaceutical Chemistry, University of California, San Francisco, San Francisco, CA 94143, USA; Chan Zuckerberg Biohub, San Francisco, CA 94148, USA; Quantitative Biosciences Institute, University of California, San Francisco, San Francisco, CA 94143, USA; Department of Anesthesia and Perioperative Care, University of California, San Francisco, San Francisco, CA 94115, USA. Electronic address:

Three proton-sensing G protein-coupled receptors (GPCRs)-GPR4, GPR65, and GPR68-respond to extracellular pH to regulate diverse physiology. How protons activate these receptors is poorly understood. We determined cryogenic-electron microscopy (cryo-EM) structures of each receptor to understand the spatial arrangement of proton-sensing residues.

View Article and Find Full Text PDF

Target-assisted self-powered photoelectrochemical sensor based on AgS/BiOCl heterojunction for ultrasensitive chlorpyrifos detection.

Talanta

December 2024

College of Geography and Environmental Sciences, College of Chemistry and Materials Sciences, Key Laboratory of Watershed Earth Surface Processes and Ecological Security, Zhejiang Normal University, Jinhua, 321004, China. Electronic address:

Chlorpyrifos (CPF), a widely used organophosphorus pesticide, presents substantial risks to both environmental and human health due to its persistent accumulation, thereby necessitating the development of effective detection methods. Self-powered photoelectrochemical (PEC) sensors, as an innovative technology, address the limitations inherent in conventional sensors, such as susceptibility to interference and inadequate signal response. Herein, we synthesized AgS/BiOCl as a photosensitive material, employing it as a light-harvesting substrate and a signal-transducing platform to develop a self-powered PEC sensor for the detection of CPF.

View Article and Find Full Text PDF

This research presents a systematic review of the application of metal-organic frameworks (MOFs) to detect volatile organic compounds (VOCs). VOCs, compounds with high vapor pressure at ambient temperature and normal pressure, are widely present in a variety of industrial and living environments. VOCs are not only hazardous to the environment but also have a severe impact on human health.

View Article and Find Full Text PDF

Qualitative and quantitative detection of sex-targeted hormones in chicken embryo based on terahertz spectroscopy and metamaterial technology.

Spectrochim Acta A Mol Biomol Spectrosc

December 2024

Intelligent Equipment Research Center, Beijing Academy of Agriculture and Forestry Sciences, Beijing 100097, China. Electronic address:

Gender identification of chick embryos at the early stages of incubation is of significant importance to poultry industry. Existing studies showed reproductive hormone concentrations are associated with gender of chick embryos. Accurate detection of reproductive hormone concentration can assist in gender identification.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!