Bis[1-meth-oxy-2,2,2-tris-(pyrazol-1-yl-κN (2))ethane]-nickel(II) bis-(tri-fluoro-methane-sulfonate) methanol disolvate.

Acta Crystallogr Sect E Struct Rep Online

Department of Biochemistry, Chemistry and Physics, Southern Arkansas University, Magnolia, AR 71753, USA.

Published: October 2013

In the title salt, [Ni(C12H14N6O)2](CF3SO3)2·2CH3OH, the Ni(II) ion is coordinated by six N atoms from two tridentate 1-meth-oxy-2,2,2-tris-(pyrazol-1-yl)ethane ligands in a distorted octa-hedral geometry. The Ni(II) ion is situated on an inversion centre. The Ni-N distances range from 2.0589 (19) to 2.0757 (19) Å, intra-ligand N-Ni-N angles range from 84.50 (8) to 85.15 (8)°, and adjacent inter-ligand N-Ni-N angles range between 94.85 (8) and 95.50 (8)°. In the crystal, O-H⋯O hydrogen bonds between methanol solvent mol-ecules and tri-fluoro-methane-sulfonate anions are observed.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790348PMC
http://dx.doi.org/10.1107/S1600536813024653DOI Listing

Publication Analysis

Top Keywords

niii ion
8
n-ni-n angles
8
angles range
8
bis[1-meth-oxy-222-tris-pyrazol-1-yl-κn 2ethane]-nickelii
4
2ethane]-nickelii bis-tri-fluoro-methane-sulfonate
4
bis-tri-fluoro-methane-sulfonate methanol
4
methanol disolvate
4
disolvate title
4
title salt
4
salt [nic12h14n6o2]cf3so32·2ch3oh
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!