In the title compound, [Pd(C11H13N3O2S)(C18H15P)]·C2H5OH, the Pd(II) atom is tetra-coordinated in a slightly distorted square-planar environment by three donor atoms (NOS) from a thio-semicarbazonate ligand, forming five- and six-membered chelate rings, and a P atom from a neutral tri-phenyl-phosphane group. The five-membered ring adopts a distorted envelope conformation with Pd(II) as the flap atom, while the six-membered ring forms a slightly twisted screw-boat conformation. A slightly distorted screw-boat form of a meth-oxy-phenyl group is fused to the six-membered ring. Weak C-H⋯O inter-actions form dimers in the asymmetric unit and along [001] which help to stabilize the crystal packing.
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| http://dx.doi.org/10.1107/S1600536813023040 | DOI Listing |
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