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Poly[diaqua[μ4-4-(isonicotinamido)phthalato]nickel(II)] displaying an sra topology. | LitMetric

Poly[diaqua[μ4-4-(isonicotinamido)phthalato]nickel(II)] displaying an sra topology.

Acta Crystallogr C

Key Laboratory of Functional Organometallic Materials, Hengyang Normal University, Department of Chemistry and Materials Science, Hengyang, Hunan 421008, People's Republic of China.

Published: October 2013

In the title compound, [Ni(C14H8N2O5)(H2O)2]n, the Ni(II) cation is six-coordinate with a slightly distorted octahedral coordination geometry and the 4-(isonicotinamido)phthalate ligand links the Ni(II) centres into a three-dimensional structure with sra topology. The structure is also stabilized by N-H···O hydrogen bonding between the uncoordinated amide groups of the ligand and extensive O-H···O hydrogen bonding between the two coordinated water molecules. The magnetic and thermal stability properties of the title compound are also discussed.

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Source
http://dx.doi.org/10.1107/S0108270113023846DOI Listing

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