Objectives: A model resin composite containing a novel monomodal inorganic filler system based on submicron-sized Ba-Si-Al glass particles (NanoFine NF180; Schott) was formulated and compared with an experimental composite containing micron-sized particles (UltraFine UF1.0; Schott).
Methods: The filler particles were characterized using X-ray microanalysis and granulometry, while the composites were characterized in terms of filler-resin morphology, radiopacity, degree of CC conversion, hardness, flexural strength/modulus, work-of-fracture, surface roughness and gloss (before and after simulated toothbrushing abrasion), and bulk compressive creep. The composites were formulated from the same photoactivated dimethacrylate co-monomer, incorporating mass fractions of 75% micron- and 78% submicron-sized particles. Quantitative data were analyzed at a significance level of p<0.05.
Results: Both filler systems exhibited a narrow grain size range (175±30 and 1000±200 nm), with differences restricted to the size and specific area of the particles. The composites were similar in radiopacity, flexural strength, work-of-fracture, and creep. The submicron composite was harder but had lower flexural modulus and CC conversion. No significant differences in roughness were observed before brushing, although the submicron composite had higher gloss. Brushing increased roughness and decreased gloss on both materials, but the submicron composite retained higher gloss after brushing.
Significance: The monomodal submicron glass filler system demonstrated potential for use in restorative dental composites, particularly due to improved esthetic properties.
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http://dx.doi.org/10.1016/j.dental.2013.09.006 | DOI Listing |
Int J Biol Macromol
January 2025
Key Laboratory of Automobile Materials, Ministry of Education, and College of Materials Science and Engineering, Jilin University, Changchun 130025, China. Electronic address:
A new type of filler was added to epoxy resin to prepare a composite coating with excellent corrosion and weathering resistance. The simple synthesis process and nonpolluting raw materials of this filler contribute to the development of green chemistry. Specifically, lignin was encapsulated in mesoporous silica, the synergistic effect between the two resulted in the formation of lignin/mesoporous silica composite particles (MSN-L) with excellent ultraviolet (UV) resistance.
View Article and Find Full Text PDFPolymers (Basel)
January 2025
Department of Chemical and Metallurgical Engineering, School of Chemical Engineering, Aalto University, 02150 Espoo, Finland.
Alginate hydrogels have gathered significant attention in biomedical engineering due to their remarkable biocompatibility, biodegradability, and ability to encapsulate cells and bioactive molecules, but much less has been reported on the kinetics of gelation. Scarce experimental data are available on cross-linked alginates (AL) with bioactive components. The present study addressed a novel method for defining the crosslinking mechanism using rheological measurements for aqueous mixtures of AL and calcium chloride (CaCl) with the presence of hydroxyapatite (HAp) as filler particles.
View Article and Find Full Text PDFPolymers (Basel)
January 2025
Materials Engineering and Welding Department, Transilvania University of Brasov, 500036 Brasov, Romania.
This review explores the impact of various additives on the mechanical properties of polylactic acid (PLA) filaments used in Fused Deposition Modeling (FDM) 3D printing. While PLA is favored for its biodegradability and ease of use, its inherent limitations in strength and heat resistance necessitate enhancements through additives. The impact of natural and synthetic fibers, inorganic particles, and nanomaterials on the mechanical properties, printability, and overall functionality of PLA composites was examined, indicating that fiber reinforcements, such as carbon and glass fibers, significantly enhance tensile strength and stiffness, while natural fibers contribute to sustainability but may compromise mechanical stability.
View Article and Find Full Text PDFMaterials (Basel)
January 2025
Division of Biomaterials, School of Dentistry, University of Alabama at Birmingham, Birmingham, AL 35209, USA.
Two 3D-printed crown materials (Crown and Ceramic Crown) were examined to determine the best surface treatment and primers for bonding. Discs of the two materials were printed and mounted with their "intaglio" surfaces untouched. Half the specimens from each group were sandblasted with 50 µm alumina.
View Article and Find Full Text PDFJ Mech Behav Biomed Mater
January 2025
Shanxi Key Laboratory of Biomedical Metal Materials, College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan, 030024, China.
Mesoporous silica particles are of great interest in the field of dental composites as functional inorganic fillers due to their unique interconnected pores which can form micromechanical interlocking at the filler-resin interfaces. However, the degradation of mesoporous silica is fast in wet environments, leading to the poor mechanical stability of dental composites. Here, we synthesized Zr-doped mesoporous silica spheres (Zr-MSS) to increase the chemical stability of the particles.
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