We demonstrate how introducing a deliberate defect on the overhanging caps of strongly adhering mushroom shaped dry adhesive fibers can produce directional adhesion behavior. We find that the shape and location of this defect controls both the total adhesion force and the degree of directionality for these bio-inspired adhesives. Linear beam theory is used to demonstrate how the application of a shear load to a fiber in tension can create a small compressive load to an asymmetric crack, thereby delaying adhesion failure and producing directional adhesion, and the theory is confirmed with finite element models and empirical data. Anisotropic adhesives have been fabricated and tested and can demonstrate normal adhesion force up to ~250 kPa with a shear displacement of 15 µm away from the defect and as small as ~5 kPa when sheared the same amount towards the defect.
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http://dx.doi.org/10.1088/1748-3182/8/4/044002 | DOI Listing |
Food Sci Nutr
January 2025
Department of Food Science and Technology, Faculty of Pharmacy, Tehran Medical Science Islamic Azad University Tehran Iran.
Pro-biogenic is a recent terminology widely used for products that combine biogenic materials and probiotics which has made progressive improvement in a new era of research on functional foods. This study aimed to develop functional ice cream with and propolis extract (PE) as a biogenic part to develop ice cream's physiochemical and antioxidant characteristics. Five probiotic ice cream samples were prepared using different levels of PE powder (0%, 0.
View Article and Find Full Text PDFPolymers (Basel)
December 2024
Faculty of Forestry, University of Belgrade, 11030 Belgrade, Serbia.
The surfaces of beech wood samples were treated with polyethylenimine (PEI) solutions at three different concentrations-0.5%, 1% and 2%-and two molecular weights-low molecular weight (LMW) and high molecular weight (HMW). The effects of PEI surface treatment of wood were characterized by FT-IR spectroscopy, the penetration depth of PEI (EPI fluorescence spectroscopy), the bonding position of PEI (by SEM), the wetting and surface energy, and the water uptake.
View Article and Find Full Text PDFPolymers (Basel)
December 2024
CNBM Zhongyan Technology Co., Ltd., Beijing 100024, China.
This study aims to develop castable polyurethane suitable for applications on wet substrates or underwater construction. Polyurethanes were synthesized using various polyols with similar hydroxyl values, including poly(tetrahydrofuran) polyol, polyester polyol, castor oil-modified polyol, soybean oil-modified polyol, and cashew nut shell oil-modified polyol. The corresponding polyurethane curing products were evaluated for their underwater curing characteristics by volume expansion ratios and adhesion strength on dry and wet substrates, combined with analyses of reaction exothermic behavior, wetting properties on dry and wet substrates, interfacial tension, and microstructure characterization from the perspectives of reaction activity and water solubility.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
Shandong Laboratory of Advanced Materials and Green Manufacturing at Yantai, Yantai 264006, PR China. Electronic address:
The pursuit of multifunctional soybean protein isolate (SPI)-based adhesives with high strength, water resistance, and resistance to mildew and flame remains a formidable scientific challenge. Inspired by mussels, in this work, quaternary ammonium salted hyperbranched polyamide (QHBPA) and polydopamine (PDA) were incorporated onto the surface of MXene. The synthesized hybrid material, namely Q-MXene, accompanied with phosphorylated chitosan (PCS), was subsequently integrated into the SPI-based adhesive to synergistically improve its performance via organic-inorganic hybridization techniques.
View Article and Find Full Text PDFTissue Cell
January 2025
Department of Biomedical Engineering, Science and Research Branch, Islamic Azad University, Tehran, Iran.
Mechanical loading plays a pivotal role in regulating bone anabolic processes. Understanding the optimal mechanical loading parameters for cellular responses is critical for advancing strategies in orthopedic bioreactor-based bone tissue engineering. This study developed a poly (sorbitol sebacate) (PSS) filmscaffold with a sorbitol-to-sebacic acid molar ratio of 1:4.
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