Hydride abstraction from monocationic hydride bridged salts [H(H2B-L)2](+) [B(C6F5)4]¯ (L = Lewis base) generates an observable primary borenium cation for L = iPr2NEt, but with L = Me3N, Me2NPr, or several N-heterocyclic carbenes, highly reactive dicationic dimers are formed.
Download full-text PDF |
Source |
---|---|
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3857331 | PMC |
http://dx.doi.org/10.1021/ja407458k | DOI Listing |
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!