The preparation of several 1,2,3,4,5-functionalized cyclopentane derivatives.

Beilstein J Org Chem

Institute of Organic Chemistry, Technical University of Braunschweig, Hagenring 30, D-38106 Braunschweig, Germany, Fax +49-(0)531-391-5288.

Published: September 2013

With the goal of eventually synthesizing [5]radialene (3), the still missing member of the parent radialene hydrocarbons, we have prepared the pentaacetates 21 and 31, the pentabromide 29 and the hexabromide 32. In principle these should be convertible by elimination reactions to the desired target molecule.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3778403PMC
http://dx.doi.org/10.3762/bjoc.9.195DOI Listing

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