AI Article Synopsis
- The study reveals the efficient catalytic hydrolysis of silanes using the chlorodicarbonylrhodium(I) dimer, [RhCl(CO)2]2, leading to the production of silanols and dihydrogen under mild conditions.
- Research findings demonstrate second-order kinetics and calculated activation parameters through the observation of dihydrogen evolution rates.
- Mixing [RhCl(CO)2]2 with HSiCl3 quickly forms a rhodium silane σ complex, indicating a fast chemical reaction.
Article Abstract
Catalytic hydrolysis of silanes mediated by chlorodicarbonylrhodium(I) dimer [RhCl(CO)2]2 to produce silanols and dihydrogen efficiently under mild conditions is reported. Second-order kinetics and activation parameters are determined by monitoring the rate of dihydrogen evolution. The mixing of [RhCl(CO)2]2 and HSiCl3 results in rapid formation of a rhodium silane σ complex.
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