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cis-Bis(O-methyl-dithio-carbonato-κ(2) S,S')bis-(tri-phenyl-phosphane-κP)ruthenium(II). | LitMetric
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cis-Bis(O-methyl-dithio-carbonato-κ(2) S,S')bis-(tri-phenyl-phosphane-κP)ruthenium(II).

Cintya Valerio-Cárdenas Simón Hernández-Ortega Reyna Reyes-Martínez David Morales-Morales

Acta Crystallogr Sect E Struct Rep Online

Instituto de Química, Universidad Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, México, D.F., 04510, Mexico.

Published: September 2013

In the title compound, [Ru(CH3OCS2)2(C18H15P)2], the Ru(II) atom is in a distorted octa-hedral coordination by two xanthate anions (CH3OCS2) and two tri-phenyl-phosphane (PPh3) ligands. Both bidentate xanthate ligands coordinate the Ru(II) atom with two slightly different Ru-S bond lengths but with virtually equal bite angles [71.57 (4) and 71.58 (3)°]. The packing of the complexes is assured by C-H⋯O and C-H⋯π inter-actions.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772435PMC
http://dx.doi.org/10.1107/S1600536813016735DOI Listing

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