The Cu(II) atom in the title compound, [Cu(C16H10ClN2O)2], is located on an inversion center and is tetra-coordinated by two N and two O atoms from two bidentate 1-[(E)-(2-chloro-phen-yl)diazen-yl]naphthalen-2-olate ligands, forming a square-planar complex. In the crystal, mol-ecules are linked via weak C-H⋯O and C-H⋯Cl hydrogen bonds, forming chains propagating along [010]. There are also π-π inter-actions present involving adjacent naphthalene rings [centroid-centroid distance = 3.661 (13) Å].
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772433 | PMC |
| http://dx.doi.org/10.1107/S1600536813016681 | DOI Listing |
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Bis{1-[(E)-(2-chloro-phen-yl)diazen-yl]naphthalen-2-olato}copper(II).
Acta Crystallogr Sect E Struct Rep Online
September 2013
Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale, (CHEMS), Faculté des Sciences Exactes, Département de Chimie, Université Constantine 1, Algeria.
The Cu(II) atom in the title compound, [Cu(C16H10ClN2O)2], is located on an inversion center and is tetra-coordinated by two N and two O atoms from two bidentate 1-[(E)-(2-chloro-phen-yl)diazen-yl]naphthalen-2-olate ligands, forming a square-planar complex. In the crystal, mol-ecules are linked via weak C-H⋯O and C-H⋯Cl hydrogen bonds, forming chains propagating along [010]. There are also π-π inter-actions present involving adjacent naphthalene rings [centroid-centroid distance = 3.
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