Direct observation of cyclic carbenium ions and their role in the catalytic cycle of the methanol-to-olefin reaction over chabazite zeolites.

Angew Chem Int Ed Engl

National Engineering Laboratory for Methanol to Olefins, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (P. R. China).

Published: October 2013

Carbenium ions in zeolites: Two important carbenium ions have been observed for the first time under working conditions of the methanol-to-olefins (MTO) reaction over chabazite zeolites using (13) C NMR spectroscopy. Their crucial roles in the MTO reaction cycles have been demonstrated by combining experiments and theoretical calculations.

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http://dx.doi.org/10.1002/anie.201303586DOI Listing

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