The marriage of fire and water: The strongly oxidizing trinitromethyl and strongly reducing BH3 groups were successfully combined for the first time in the novel [BH3 C(NO2 )3 ](-) ion. The stability at room temperature of the new (trinitromethyl)borate is in sharp contrast to the behavior of [BCl3 C(NO2 )3 ](-) , which already decomposes at -20 °C.
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[BH(3)C(NO(2))(3)](-) : the first room-temperature stable (trinitromethyl)borate.
Angew Chem Int Ed Engl
October 2013
Loker Hydrocarbon Research Institute, Department of Chemistry, University of Southern California, Los Angeles, CA 90089-1661 (USA).
The marriage of fire and water: The strongly oxidizing trinitromethyl and strongly reducing BH3 groups were successfully combined for the first time in the novel [BH3 C(NO2 )3 ](-) ion. The stability at room temperature of the new (trinitromethyl)borate is in sharp contrast to the behavior of [BCl3 C(NO2 )3 ](-) , which already decomposes at -20 °C.
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