Alkene to carbyne: tandem Lewis acid activation and dehydrogenation of a molybdenum ethylene complex.

Angew Chem Int Ed Engl

School of Chemistry, University of Bristol, Cantock's Close BS8 1TS (UK) http://www.wassresearchgroup.com.

Published: October 2013

Carbyne formation: Treatment of a molybdenum ethylene complex with B(C6 F5 )3 induces ditopic activation of an ethylene ligand and acceptor-assisted ethane elimination to generate a novel type of zwitterionic carbyne complex.

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http://dx.doi.org/10.1002/anie.201305233DOI Listing

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