Two neutral hexanuclear trigonal prismatic cage molecules have been synthesized by coupling two planar triangular M3pz3-panels, M = Cu(I) and Ag(I), in eclipsed geometry. The ~230 Å(3) cage volume can be either vacant or occupied by neutral guests. The crystal structures of the M6-cyclohexane and Ag6-S8 host-guest species have been determined.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1039/c3dt51332g | DOI Listing |
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!