Two neutral hexanuclear trigonal prismatic cage molecules have been synthesized by coupling two planar triangular M3pz3-panels, M = Cu(I) and Ag(I), in eclipsed geometry. The ~230 Å(3) cage volume can be either vacant or occupied by neutral guests. The crystal structures of the M6-cyclohexane and Ag6-S8 host-guest species have been determined.

Download full-text PDF

Source
http://dx.doi.org/10.1039/c3dt51332gDOI Listing

Publication Analysis

Top Keywords

trigonal prismatic
8
cui agi
8
prismatic cui
4
agi pyrazolato
4
pyrazolato nanocage
4
nanocage hosts
4
hosts encapsulation
4
encapsulation hydrocarbon
4
hydrocarbon guests
4
guests neutral
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!