Extreme-rate capable and highly stable SiCO-TiO2 hybrids for Li ion battery anodes.

Chem Commun (Camb)

Department of Mechanical Engineering, University of Colorado, UCB 427, Boulder, CO 80309, USA.

Published: October 2013

A novel hybrid material for Li ion battery anodes, synthesized from polysiloxane-derived SiCO and nanoparticulate TiO2, exhibited specific capacity in excess of 850 mA h g(-1), fully recoverable capacity after cycling at severe current densities, as high as 20,000 mA g(-1) or 300 C rate, and exceptional stability beyond 1000 charge discharge cycles without capacity fading. Microscopy of the anodes after 3000 cycles showed no degradation or loss of materials.

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Source
http://dx.doi.org/10.1039/c3cc45311aDOI Listing

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