Modelling electric field control of the spin state in the mixed-valence polyoxometalate [GeV14O40]8-.

Chem Commun (Camb)

Instituto de Ciencia Molecular (ICMol), Universidad de Valencia, C/Catedrático José Beltrán No 2, 46980 Paterna, Spain.

Published: October 2013

The two-electron reduced mixed-valence polyoxometalate [GeV14O40](8-) presents an unusual paramagnetic behaviour as a consequence of the partial trapping of these electrons. The effect of applying an electric field is that of inducing antiferromagnetic coupling between the two delocalized electronic spins.

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Source
http://dx.doi.org/10.1039/c3cc44859bDOI Listing

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