Synthesis of aryl trimethylstannanes from aryl amines: a Sandmeyer-type stannylation reaction.

Angew Chem Int Ed Engl

Beijing National Laboratory of Molecular Sciences (BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871 (China).

Published: October 2013

Sandmeyer-type stannylation: Stille coupling is one of the most powerful coupling reactions for CC bond formation, whereas there are only limited methods to access aryl stannane compounds. A mild stannylation process based on a Sandmeyer-type transformation using aromatic amines as the starting materials is described. DCE: 1,2-dichloroethane.

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http://dx.doi.org/10.1002/anie.201304579DOI Listing

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Synthesis of aryl trimethylstannanes from aryl amines: a Sandmeyer-type stannylation reaction.

Angew Chem Int Ed Engl

October 2013

Beijing National Laboratory of Molecular Sciences (BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871 (China).

Sandmeyer-type stannylation: Stille coupling is one of the most powerful coupling reactions for CC bond formation, whereas there are only limited methods to access aryl stannane compounds. A mild stannylation process based on a Sandmeyer-type transformation using aromatic amines as the starting materials is described. DCE: 1,2-dichloroethane.

View Article and Find Full Text PDF

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