We study the winding and unwinding of Saturn ring defects around silica microspheres with homeotropic surface anchoring in a cholesteric liquid crystal with a variable pitch. We use mixtures of a nematic liquid crystal 5CB and various photoresponsive chiral dopants to vary the helical pitch and sense of the helical winding by illuminating the mixtures with UV or visible light. Upon illumination, we observe motion of the Grandjean-Cano disclination lines in wedge-like cells. When the line touches the colloidal particle, we observe topological reconstruction of the Grandjean-Cano line and the Saturn ring. The result of this topological reconstruction is either an increase or decrease of the degree of winding of the Saturn ring around the colloidal particle. This phenomenon is similar to topological rewiring of -1/2 disclination lines, observed recently in chiral nematic colloids.
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http://dx.doi.org/10.1140/epje/i2013-13097-8 | DOI Listing |
Nat Commun
December 2024
Institute of Space Physics and Applied Technology, Peking University, Beijing, China.
The drift motion of energetic charged particles can generate an azimuthal electric current around the planet known as the ring current, which regulates the field configuration of the magnetosphere. However, limited coverage of in-situ measurements makes it challenging to investigate the long-term variations of the global ring current. Taking advantage of the energetic neutral atom (ENA) imaging onboard the Cassini mission, we present a nearly 11-year cycle of the suprathermal ring current populations in Saturn's magnetosphere.
View Article and Find Full Text PDFJ Phys Chem A
August 2024
Dipartimento di Chimica Biologia e Biotecnologie, Università degli Studi di Perugia, 06123 Perugia, Italy.
Despite the relevance of the reactions of the prototypical nitrogen-containing six-membered aromatic molecule (N-heterocyclic) of pyridine (CHN) in environmental science, astrochemistry, planetary science, prebiotic chemistry, and materials science, few experimental/theoretical studies exist on the bimolecular reactions involving pyridine and neutral atomic/molecular radicals. We report a combined experimental and theoretical study on the elementary reaction of pyridine with excited nitrogen atoms, N(D), aimed at providing information about the primary reaction products and their branching fractions (BFs). From previous crossed molecular beam (CMB) experiments with mass-spectrometric detection and present synergistic calculations of the reactive potential energy surface (PES) and product BFs we have unveiled the reaction mechanism.
View Article and Find Full Text PDFChemistry
October 2024
Beijing Kein Research Center for Natural Sciences, Beijing, 100022, People's Republic of China.
This work conducts a comprehensive theoretical study on the non-covalent complexation between cyclocarbons and C fullerene for the first time. The binding energy between cyclocarbons and C fullerene is significantly stronger than that between two C or two C fullerenes, indicating a particularly strong affinity. The cyclocarbons and C fullerene can spontaneously assemble into complexes in the gas phase at room temperature, and the hydrophobic effect caused by the solvent environment can promote this binding.
View Article and Find Full Text PDFOne of the stranger planetary rings is Saturn's narrow, clumpy F ring, lying just outside the main rings, in a region disturbed by chaotic orbital dynamics. We show that the F ring has a stable "true core" that dominates its mass and is confined into discontinuous short arcs of particles larger than a few millimeters in radius. The more obvious micron-size particles seen in images, outlining and obscuring the true core, contribute only a small fraction of its mass.
View Article and Find Full Text PDFChem Commun (Camb)
February 2024
Division of Molecular Science, Faculty of Science and Technology, Gunma University, 1-5-1 Tenjin-cho, Kiryu, Gunma 376-8515, Japan.
Phenothiazine cyclic hexamers linked at the 3,7-positions were synthesized. Effects of the cyclic structure as well as substituent effects of the nitrogen atom were disclosed. Furthermore, the cyclic hexamer encapsulated C inside the ring in a 1 : 1 ratio giving a Saturn-type complex in solution.
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