A facile and cost-effective approach for the fabrication of a hierarchical nanocomposite material of graphene-wrapped MnO2 -graphene nanoribbons (GMG) is developed. The resulting composite has a high specific capacity and an excellent cycling stability owing to the synergistic combination of the electrically conductive graphene, graphene nanoribbons, and MnO2 .
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http://dx.doi.org/10.1002/adma.201302915 | DOI Listing |
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August 2018
Laboratory of Advanced Materials, Department of Materials Science and Collaborative Innovation Center of Chemistry for Energy Materials, Fudan University, Shanghai, 200438, P. R. China.
The ingenious design of a freestanding flexible electrode brings the possibility for power sources in emerging wearable electronic devices. Here, reduced graphene oxide (rGO) wraps carbon nanotubes (CNTs) and rGO tightly surrounded by MnO nanosheets, forming a 3D multilevel porous conductive structure via vacuum freeze-drying. The sandwich-like architecture possesses multiple functions as a flexible anode for lithium-ion batteries.
View Article and Find Full Text PDFChemistry
May 2016
State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Science, Changchun, 130022, P. R. China.
A simple synthetic approach for graphene-templated nanostructured MnO2 nanowires self-inserted with Co3 O4 nanocages is proposed in this work. The Co3 O4 nanocages were penetrated in situ by MnO2 nanowires. As an anode, the as-obtained MnO2 -Co3 O4 -RGO composite exhibits remarkable enhanced performance compared with the MnO2 -RGO and Co3 O4 -RGO samples.
View Article and Find Full Text PDFAnal Bioanal Chem
October 2015
Department of Chemistry and Chemical Engineering, Hubei Key Laboratory of Material Chemistry and Service Failure, Huazhong University of Science & Technology, Wuhan, 430074, China.
We report the design and fabrication of a new type of nanohybrid microelectrode based on a hierarchical nanostructured Au/MnO2/graphene-modified carbon fiber (CF) via in situ electrochemical synthesis, which leads to better structural integration of different building blocks into the CF microelectrode. Our finding demonstrates that wrapping CF with graphene nanosheets has dramatically increased the surface area and electrical conductivity of the CF microelectrode. The subsequent template-free electrodeposition of MnO2 on graphene-wrapped CF gives rise to a porous nanonest architecture built up from twisted and intersectant MnO2 nanowires, which serves as an ideal substrate for the direct growth of Au nanoparticles.
View Article and Find Full Text PDFSci Rep
July 2015
Department of Physical Chemistry Engineering, M. V. Lomonosov Moscow State University, Moscow 119991, Russia.
LiNi0.5Mn1.5O4 nanorods wrapped with graphene nanosheets have been prepared and investigated as high energy and high power cathode material for lithium-ion batteries.
View Article and Find Full Text PDFAdv Mater
November 2013
Department of Chemistry, Rice University, 6100 Main Street MS 60, Houston, Texas, 77005, USA.
A facile and cost-effective approach for the fabrication of a hierarchical nanocomposite material of graphene-wrapped MnO2 -graphene nanoribbons (GMG) is developed. The resulting composite has a high specific capacity and an excellent cycling stability owing to the synergistic combination of the electrically conductive graphene, graphene nanoribbons, and MnO2 .
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