CarAlg/MMt nanocomposite hydrogels composed of kappa-carrageenan (Car) and sodium alginate (Alg) biopolymers were synthesized by incorporation of sodium montmorillonite (Na-MMt) nanoclay. Acrylamide (AAm), methylenebisacrylamide (MBA), and ammonium persulfate (APS) were used as monomer, crosslinker, and initiator, respectively. The structure and morphology of nanocomposites were characterized by XRD, SEM, and TEM techniques. The XRD results showed exfoliated MMt nanoclay and exfoliation of MMt was confirmed by TEM graph. The resulting nanocomposites were evaluated to remove cationic crystal violet (CV) dye from water. According to data, the adsorption capacity of nanocomposites was enhanced as the clay content was increased. The experimental data were analyzed according to both Langmuir and Freundlich models and experimental maximum adsorption capacity was obtained 88.8 mg g(-1). By studying the effect of pH on the dye adsorption capacity of nanocomposites, it was revealed that the adsorption capacity of nanocomposites was enhanced at acidic pHs as the Na-MMt nanoclay and kappa-carrageenan components were increased.
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http://dx.doi.org/10.1016/j.carbpol.2013.05.096 | DOI Listing |
Anal Chim Acta
February 2025
State Key Laboratory of Applied Organic Chemistry and Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, College of Chemistry and Chemical Engineering, Lanzhou University, Gansu, Lanzhou, 730000, China. Electronic address:
The presence of lead ion (Pb) in groundwater poses a serious risk to human health, even at low levels. Therefore, it is essential to develop a new strategy for both selective detection and effective removal of Pb in groundwater, which has been rarely reported. Here, we developed a multi-functional chitosan-based fluorescent sensing membrane (CM-L/CG) by using a casting method for the sensitive/selective detection and removal of Pb in groundwater.
View Article and Find Full Text PDFEnviron Pollut
January 2025
Department of Mineral Processing Engineering, Taiyuan University of Technology, Taiyuan 030024, China.
To realize the comprehensive utilization of large amounts of high-ash coal slime and comprehensively understand the excellent performance of nutrient release and lead and cadmium adsorption of high-ash coal slime silicon composite materials, green and safe mild hydrothermal conditions (200 °C) were used to prepare the rich-rich coal slime. Zeolite/tobermorite composites (Z-TOBs) were used in this study. Batch adsorption tests and repeated extraction tests were used to determine whether silicon, potassium, and calcium nutrients of Z-TOBs have sustained release properties and are affected by pH.
View Article and Find Full Text PDFAdv Colloid Interface Sci
January 2025
School of Metallurgy and Environment, Central South University, Changsha 410083, Hunan, China; Chinese National Engineering Research Center for Control & Treatment of Heavy Metal Pollution, Institute of Environmental Engineering, Central South University, Changsha 410083, Hunan, China.
Rare earth elements (REEs) are crucial metallic resources that play an essential role in national economies and industrial production. The reclaimation of REEs from wastewater stands as a significant supplementary strategy to bolster the REEs supply. Adsorption techniques are widely recognized as environmentally friendly and sustainable methods for the separation of REEs from wastewater.
View Article and Find Full Text PDFJ Hazard Mater
January 2025
College of the Environment and Ecology, Xiamen University, Xiamen 361005, China; Fujian Provincial Key Laboratory for Coastal Ecology and Environmental Studies, Xiamen University, Xiamen 361005, China. Electronic address:
Due to the high toxicity and increasing consumption, efficient removal of phenoxyacetic acid herbicides (PAAHs) from water is imperative. In current study, a new adsorbent was prepared by modifying porous carbon derived from disused floral foam with chitosan (CS) (ACFC). Density functional theory (DFT) calculation uncovered that the amino and hydroxyl groups in the introduced CS played a critical role in the efficient adsorption of ACFC towards PAAHs.
View Article and Find Full Text PDFChemosphere
January 2025
DASCO Inc, Centennial, Colorado, USA.
This study thoroughly investigated the adsorption of Congo Red (CR) dye onto various microplastics (MPs), including high-density polyethylene (HDPE), polyvinyl chloride (PVC), low-density polyethylene (LDPE), polypropylene (PP) and polyethylene terephthalate (PET). Initial adsorption capacities (q) revealed that HDPE had the highest value (21.90 mg/g), followed by PVC (4.
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