Colloidal Au@ZnO hybrid nanocrystals with linear and branched shape were synthesized. The number of ZnO domains on the Au seeds can be controlled by the solvent mixture. Imidazole-functionalized Au@ZnO hybrid nanocrystals were soluble in water and exhibited a greatly enhanced photocatalytic activity compared to ZnO nanocrystals. The pristine heterodimeric NPs were characterized using transmission electron microscopy (TEM), X-ray diffraction (XRD), and UV-Vis spectroscopy.
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http://dx.doi.org/10.1039/c3nr02817h | DOI Listing |
J Nanobiotechnology
May 2024
Department of Laboratory Medicine, Shanghai Medical College, Huashan Hospital, Fudan University, Shanghai, 200040, China.
Zinc oxide nanoparticles (ZnO NPs) stand as among the most significant metal oxide nanoparticles in trigger the formation of reactive oxygen species (ROS) and induce apoptosis. Nevertheless, the utilization of ZnO NPs has been limited by the shallowness of short-wavelength light and the constrained production of ROS. To overcome these limitations, a strategy involves achieving a red shift towards the near-infrared (NIR) light spectrum, promoting the separation and restraining the recombination of electron-hole (e-h) pairs.
View Article and Find Full Text PDFJ Chem Phys
December 2023
School of Physics, Indian Institute of Science Education and Research Thiruvananthapuram, Thiruvananthapuram, Kerala 695551, India.
Modeling light-matter interactions in hybrid plasmonic materials is vital to their widening relevance from optoelectronics to photocatalysis. Here, we explore photoluminescence (PL) from ZnO nanorods (ZNRs) embedded with gold nanoparticles (Au NPs). A progressive increase in Au NP concentration introduces significant structural disorder and defects in ZNRs, which paradoxically quenches defect related visible PL while intensifying the near band edge (NBE) emission.
View Article and Find Full Text PDFHeliyon
December 2023
Institute of Microengineering and Nanoelectronics (IMEN), Universiti Kebangsaan Malaysia, 43600, UKM Bangi, Selangor, Malaysia.
Uric acid is a waste product of the human body where high levels of it or hyperuricemia can lead to gout, kidney disease and other health issues. In this paper, Finite Difference Time Doman (FDTD) simulation method was used to develop a plasmonic optical sensor to detect uric acid with molarity ranging from 0 to 3.0 mM.
View Article and Find Full Text PDFNanomaterials (Basel)
August 2023
College of Materials Science and Engineering, China Jiliang University, Hangzhou 310018, China.
To improve the gas sensitivity of reduced oxide graphene (rGO)-based NO room-temperature sensors, different contents (0-3 wt%) of rGO, ZnO rods, and noble metal nanoparticles (Au or Ag NPs) were synthesized to construct ternary hybrids that combine the advantages of each component. The prepared ZnO rods had a diameter of around 200 nm and a length of about 2 μm. Au or Ag NPs with diameters of 20-30 nm were loaded on the ZnO-rod/rGO hybrid.
View Article and Find Full Text PDFPolymers (Basel)
March 2023
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilova St., 119991 Moscow, Russia.
One-pot synthesis of colloidal Au/ZnO and Ag/ZnO nanohybrid structures was carried out. The copolymers of maleic acid-poly(N-vinyl-2-pyrrolidone--maleic acid), poly(ethylene--maleic acid), or poly(styrene--maleic acid) were used as templates for the sorption of cations of metals-precursors and stabilization of the resulting nanoheterostructures. Simultaneous production of two types of nanoparticles has been implemented under mild conditions in an aqueous alkaline medium and without additional reagents.
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