CO2 storage efficiency is a metric that expresses the portion of the pore space of a subsurface geologic formation that is available to store CO2. Estimates of storage efficiency for large-scale geologic CO2 storage depend on a variety of factors including geologic properties and operational design. These factors govern estimates on CO2 storage resources, the longevity of storage sites, and potential pressure buildup in storage reservoirs. This study employs numerical modeling to quantify CO2 injection well numbers, well spacing, and storage efficiency as a function of geologic formation properties, open-versus-closed boundary conditions, and injection with or without brine extraction. The set of modeling runs is important as it allows the comparison of controlling factors on CO2 storage efficiency. Brine extraction in closed domains can result in storage efficiencies that are similar to those of injection in open-boundary domains. Geomechanical constraints on downhole pressure at both injection and extraction wells lower CO2 storage efficiency as compared to the idealized scenario in which the same volumes of CO2 and brine are injected and extracted, respectively. Geomechanical constraints should be taken into account to avoid potential damage to the storage site.
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http://dx.doi.org/10.1021/es4017014 | DOI Listing |
Science
January 2025
Department of Earth System Science, Stanford University, Stanford, CA, USA.
Achieving net-zero greenhouse gas emissions likely entails not only lowering emissions but also deploying carbon dioxide (CO) removal technologies. We explored the annual potential to store CO in building materials. We found that fully replacing conventional building materials with CO-storing alternatives in new infrastructure could store as much as 16.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Department of Chemical and Biomolecular Engineering, National University of Singapore, Singapore 117580, Singapore.
Hydrate-based carbon capture and storage (HBCS) is a sustainable and promising approach to combating global warming by utilizing water, which is a ubiquitous resource. Here, we report a comprehensive study of CO hydrate formation in dry water (DW), a water-in-air dispersion confined in silica particles, for improving the kinetics of hydrate growth. Utilizing a combination of a home-built high-pressure reactor, in situ Raman spectroscopy, and powder X-ray diffraction (PXRD), we elucidate the crystal structure, growth dynamics, and morphology of CO hydrates formed in DW, with and without the kinetic hydrate promoter, l-tryptophan.
View Article and Find Full Text PDFAcc Chem Res
January 2025
Smith School of Chemical and Biomolecular Engineering, Cornell University, Ithaca, New York 14853, United States.
Langmuir
January 2025
BMI Center for Biomass Materials and Nanointerfaces, National Engineering Laboratory for Clean Technology of Leather Manufacture, Ministry of Education Key Laboratory of Leather Chemistry and Engineering, College of Biomass Science and Engineering, Sichuan University, Chengdu, Sichuan 610065, China.
The growing demand for energy storage batteries, driven by the need to alleviate global warming and reduce fossil fuel dependency, has led to environmental concerns surrounding spent batteries. Efficient recycling of these batteries is essential to prevent pollution and recover valuable metal ions such as nickel (Ni), cobalt (Co), and manganese (Mn). Conventional hydrometallurgical methods for battery recycling, while effective, often involve harmful chemicals and processes.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Tianjin University of Technology, Institute for New Energy Materials and Low Carbon Technologies, 300384, Tianjin, CHINA.
Porous supramolecular crystalline materials (PSCMs), usually including hydrogen-bonded organic frameworks (HOFs), π frameworks, and so on, can be defined as a type of porous supramolecular assemblies stabilized by hydrogen-bonding, π-π stacking and other non-covalent interactions. Given the unique features of mild synthetic conditions, well-defined and tailorable structures, easy healing and regeneration, PSCMs have captured widespread interest in molecular recognition, sensor, gas storage and separation, and so on. Moreover, they currently emerge as promising photocatalysts because it is readily to endow PSCMs with photo-function, and the hydrogen-bonding and π-π stacking can serve as electron transfer channels to boost photocatalytic activity.
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