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N-heterocyclic carbene catalyzed regioselective oxo-acyloxylation of alkenes with aromatic aldehydes: a high yield synthesis of α-acyloxy ketones and esters. | LitMetric
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N-heterocyclic carbene catalyzed regioselective oxo-acyloxylation of alkenes with aromatic aldehydes: a high yield synthesis of α-acyloxy ketones and esters.

Rambabu N Reddi Pushpa V Malekar Arumugam Sudalai

Org Biomol Chem

Chemical Engineering and Process Development Division, National Chemical Laboratory (CSIR), Pashan Road, Pune, 411008, India.

Published: October 2013

An N-heterocyclic carbene (NHC)-catalyzed reaction of alkenes with aromatic aldehydes providing for a high yield synthesis of α-acyloxy ketones and esters has been described. This unprecedented regioselective oxidative process employs NBS and Et3N in stoichiometric amounts and O2 (1 atm) as an oxidant under ambient conditions in DMSO as a solvent.

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 Source
http://dx.doi.org/10.1039/c3ob41551aDOI Listing

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