Surface sediments from marine reserves of the Tuscan Archipelago National Park (Italy), including remote islands not directly affected by anthropogenic influences, were analyzed for two dominant perfluorinated compounds (PFCs), namely perfluorooctane sulfonate (PFOS) and perfluorooctanoate (PFOA), using LC-ESI-MS/MS. The concentrations of PFOS were low, with medians ranging from 0.25 to 1.50 ng/g dry wt, whereas PFOA was always below the detection limit of 0.1 ng/g dry wt. The present paper can be considered a baseline study useful in future environmental monitoring programs.
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http://dx.doi.org/10.1016/j.marpolbul.2013.07.051 | DOI Listing |
Environ Sci Technol
January 2025
Department of Civil and Environmental Engineering, University of Missouri, Columbia, Missouri 65211, United States.
Recent regulations on perfluorinated compounds in drinking water underscore the need for a deeper understanding of the formation of perfluorinated compounds from polyfluoroalkyl substances during chlorine disinfection. Among the compounds investigated in this study, N-(3-(dimethylaminopropan-1-yl)perfluoro-1-hexanesulfonamide (N-AP-FHxSA) underwent rapid transformation during chlorination. Within an hour, it produced quantitative yields of various poly- and per-fluorinated products, including perfluorohexanoic acid (PFHxA).
View Article and Find Full Text PDFAdv Sci (Weinh)
January 2025
Hunan Joint International Research Center for Carbon Dioxide Resource Utilization, School of Physics, Central South University, Changsha, Hunan, 410083, P. R. China.
Perfluorinated compounds (PFCs) are emerging environmental pollutants characterized by their extreme stability and resistance to degradation. Among them, tetrafluoromethane (CF) is the simplest and most abundant PFC in the atmosphere. However, the highest C─F bond energy and its highly symmetrical structure make it particularly challenging to decompose.
View Article and Find Full Text PDFFront Endocrinol (Lausanne)
January 2025
Department of Pediatrics, Hainan Medical University School of Pediatrics, Hainan Women and Children's Medical Center, Haikou, Hainan, China.
Background And Objective: The incidence of central precocious puberty (CPP) in girls increased significantly during the COVID-19 pandemic. This study aimed to explore the impact of perfluorinated endocrine disruptors on CPP through metabolomics analysis in girls from Hainan Province, China.
Methods: Serum samples from 100 girls with CPP and 100 healthy controls were collected.
Molecules
December 2024
Institute of Meteorology and Water Management, National Research Institute, Waszyngtona 42, 81-342 Gdynia, Poland.
In this study, the results of a comprehensive assessment of the variability in the occurrence of ten perfluorinated compounds (PFAS) in fish tissues originating from 2014 to 2019 from six fisheries in the Baltic Sea are presented. A total of 360 fish samples of three species (perch, herring and flatfish) were analysed. For the determination of PFAS, both linear and branched stereoisomers, LC-ESI-MS/MS technique preceded by simultaneous SPE isolation was validated and applied.
View Article and Find Full Text PDFReprod Toxicol
December 2024
Department of Basic Medicine, School of Medicine, Xiamen University, Xiamen, Fujian 361102, China. Electronic address:
Per- and polyfluoroalkyl substances (PFAS) are synthetic perfluorinated compounds known for their persistence in the environment and reproduction toxicity. PFAS, perfluorooctanoic acid (PFOA) and perfluorooctane sulfonate (PFOS), have been identified in the follicular fluid of infertile women. However, the specific of PFOA and PFOS mixture on oocyte quality and female fertility remain unclear.
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