Modular synthesis of all-substituted furans through oxidative carbonylation of cyclopropenes with tandem metal relay catalysis.

Chuanling Song Shuli Dong Lei Feng Xianglong Peng Mingchao Wang Jianwu Wang Zhenghu Xu

Org Biomol Chem

Key Lab for Colloid and Interface Chemistry of Education Ministry, School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, People's Republic of China.

Published: October 2013

A modular synthesis of tetrasubstituted furan carboxylates using a tandem cycloisomerization/oxidative carbonylation sequence of cyclopropenes has been successfully developed. The Tandem Metal Relay Catalysis (TMRC) pathway accounted for the high efficiency of this transformation.

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http://dx.doi.org/10.1039/c3ob41155a	DOI Listing

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