Carboxylate assistance for catalyzed hydroarylations of methylenecyclopropanes.

Org Lett

Institut für Organische und Biomolekulare Chemie, Georg-August-Universität, Tammannstrasse 2, 37077 Göttingen, Germany.

Published: September 2013

Carboxylate assistance enabled efficient and chemoselective ruthenium(II)-catalyzed hydroarylations and hydroalkenylations of highly strained methylenecyclopropanes via C-H bond activation occurring with ring conservation of the cyclopropane moieties.

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http://dx.doi.org/10.1021/ol402037fDOI Listing

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