NaYF4:Yb,Tm@TiO₂ core-shell composites were synthesized via a facile hydrothermal method. The highly crystalline TiO₂ shell can be uniformly coated onto lanthanide-doped NaYF₄ microrods and nanorods under mild conditions without calcination. The thickness of the TiO₂ shell can be tuned by varying the ratio of fluoride rods and Ti precursors. The microcomposite with a moderate TiO₂ shell shows excellent photocatalytic activity under near-infrared irradiation.
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| http://dx.doi.org/10.1039/c3nr03051b | DOI Listing |
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