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Curr Med Res Opin
December 2024
Atherosclerosis and Vascular Biology Laboratory (Aterolab), Division of Cardiology, State University of Campinas (Unicamp), Sao Paulo, Brazil.
Background: White coat effect (WCE) is a phenomenon linked to increased cardiovascular risk, where office blood pressure readings exceed home or ambulatory measurements. Excess weight and elevated blood pressure or glucose are associated with WCE in type 2 diabetes (T2D). This study compared dapagliflozin and glibenclamide on WCE in T2D patients under equivalent blood pressure and glucose control.
View Article and Find Full Text PDFJ Arthroplasty
September 2024
Department of Orthopaedic Surgery, Rothman Orthopaedic Institute, Thomas Jefferson University Hospital, Philadelphia, Pennsylvania.
Background: The prior authorization (PA) process is often criticized by physicians due to increased administrative burden and unnecessary delays in treatment. The effects of PA policies on total hip arthroplasty (THA) and total knee arthroplasty (TKA) have not been well described. The purpose of this study was to analyze the use of PA in a high-volume orthopaedic practice across 4 states.
View Article and Find Full Text PDFChem Biodivers
April 2024
Institute of POM-based Materials, New Materials and Green Manufacturing Talent Introduction and Innovation Demonstration Base, School of Materials and Chemical Engineering, Hubei University of Technology, Wuhan, 430068, Hubei, PR China.
Polyoxometalates (POMs) are promising inorganic drug candidates for cancer chemotherapy. They are becoming attractive because of their easy accessibility and low cost. Herein, we report the synthesis and antitumor activity studies of four Lindqvist-type POMs with mixed-addenda atoms Na[VWO{(OCH)CR}] (R=-CHOH, -CH, -CHCH) and (BuN)[VW{(OCH)CHOOCCHCH}].
View Article and Find Full Text PDFMaterials (Basel)
December 2023
Department of Chemistry, Faculty of Informatics and Sciences, University of Oradea, 1 Universitatii Str., 410087 Oradea, Romania.
Nowadays, choosing a corrosion inhibitor is not only based on efficiency, but must also consider the toxicity of the compound, the impact on the environment, and, obviously, the regulations in the field. In the last two decades, a special class of substances has begun to be studied, namely polyoxometalates (POMs). Their electronic properties and redox characteristics make the polyoxometalates potential candidates to be used in many electrochemical processes, and as potential corrosion inhibitors.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2023
College of Chemistry and Chemical Engineering, Advanced Catalytic Engineering Research Center of the Ministry of Education, Hunan University, Changsha 410082, P. R. China.
In addition to improving the synthetic efficiency, the template method can do a lot more in the chemistry of polyoxopalladates (POPs), such as the establishment of novel metal-oxo scaffolds. In this endeavor, a binary system comprising heterogroups of nonmetallic {As/SiO} and metallic {VO} successfully fulfills the templated growth of two POPs with unprecedented seesaw- and spindle-like prototypes. Of these, self-aggregation of heterogroups beacons an effective route to break the highly symmetrical Pd-oxo matrix and to force the arrangement of addenda in a nonconventional manner.
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